Dataset : Boosting 1H and 13C NMR signals by orders of magnitude on a bench

<h1><strong>Spectroscopic Data DNP 1T 77K</strong></h1> <p><strong>1H DNP Juice with TEMPOL at 50mM</strong></p> <p><em>Sample : 6/2/2 DMSO-d6/H2O/D2O 200&micro;L</em></p> <p><em>Topspin Folder : 20231102_HDNPjuice_50mM_CB</em></p> <p><em>Note : no phc1 in the data processing not to affect the integral as we have a broad signal</em></p> <ul> <li>TE : 100 / 200 / 300</li> <ul> <li>substraction of the 100 TE and 1000 BG with Topspin &mdash;&gt; exp 1</li> <li>For 200 w BG1000 &mdash;&gt; exp 2 proc 999</li> <li>For 300 w BG1000 &mdash;&gt; exp 3 proc 999</li> </ul> </ul> <ul> <li>DNP : 105 / 205 / 305</li> <ul> <li>MW 28,16 GHz &plusmn; 20 MHz @ 60 kHz</li> <li>E 105 (comp to 2) : 110</li> <li>E 205 (comp to 3) : 97</li> <li>E 305 (comp to 4) : 95</li> </ul> </ul> <ul> <li>T build up with satrec : 206</li> <ul> <li>28,18 GHz no fmod</li> </ul> </ul> <p>&nbsp; General model:</p> <p>&nbsp;&nbsp; &nbsp; val(t) = a*(1-exp(-(t)/T)+d)</p> <p>&nbsp;&nbsp; &nbsp; Coefficients (with 95% confidence bounds):</p> <p>&nbsp;&nbsp; &nbsp; &nbsp; T =&nbsp; &nbsp; &nbsp; 0.5164&nbsp; (0.4523, 0.5805)</p> <p>&nbsp;&nbsp; &nbsp; &nbsp; a =&nbsp; &nbsp; &nbsp; 0.7312&nbsp; (0.6996, 0.7628)</p> <p>&nbsp;&nbsp; &nbsp; &nbsp; d =&nbsp; &nbsp; &nbsp; 0.3518&nbsp; (0.3163, 0.3873)</p> <ul> <li>T1 : 207</li> <ul> <li>satrec experiment at TE</li> <li>General model:</li> <li>&nbsp;&nbsp; &nbsp; val(t) = a*(1-exp(-(t)/T)+d)</li> <li>&nbsp; &nbsp; Coefficients (with 95% confidence bounds):</li> <li>&nbsp;&nbsp; &nbsp; &nbsp; T =&nbsp; &nbsp; &nbsp; 0.5067&nbsp; (0.4584, 0.555)</li> <li>&nbsp; &nbsp; &nbsp; &nbsp; a =&nbsp; &nbsp; &nbsp; 0.7826&nbsp; (0.7567, 0.8085)</li> <li>&nbsp; &nbsp; &nbsp; &nbsp; d =&nbsp; &nbsp; &nbsp; 0.2713&nbsp; (0.2458, 0.2967)</li> </ul> </ul>