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Exposed area dependent PEC performance of BiVO4 photoanodes for solar water splitting

#Data set of "Exposed area dependent PEC performance of BiVO4 photoanodes for solar water splitting" --- ## GENERAL INFORMATION 1. Data set title: "Exposed area dependent PEC performance of BiVO4 photoanodes for solar water splitting" 2.Authorship:     Name: Christian Robles    Institution: Institute of Advanced Materials (INAM), Universitat Jaume I, 12006, Castelló, Spain    ORCID: 0000-0003-1166-2950    Name: Laura Montañés    Institution: Institude of Advanced Materials (INAM), Universitat Jaume I, 12006, Castelló, Spain    ORCID: 0000-0002-1076-013X         Name: Camilo A. Mesa    Institution: Institude of Advanced Materials (INAM), Universitat Jaume I, 12006, Castelló, Spain    ORCID: 0000-0002-8450-2563    Name: Ana Gutiérrez-Blanco    Institution: Institude of Advanced Materials (INAM), Universitat Jaume I, 12006, Castelló, Spain    ORCID: 0000-0001-9412-2321    Name: Francisco Fabregat-Santiago    Institution: Institude of Advanced Materials (INAM), Universitat Jaume I, 12006, Castelló, Spain     ORCID: 0000-0002-7503-1245    Name: Agustín O Alvarez    Institution: Institude of Advanced Materials (INAM), Universitat Jaume I, 12006, Castelló, Spain     ORCID:0000-0002-0920-5390    Name: Sixto Giménez    Institution: Institude of Advanced Materials (INAM), Universitat Jaume I, 12006, Castelló, Spain    ORCID: 0000-0002-4522-3174    Email: <sjulia@uji.es> ##FILE DESCRIPTION --------------- ### Figure 1 -Fig1a.txt : Average photocurrent–voltage (J–V) plots measured by back illumination in 0.1 M KPi with 0.1 M Na2SO3 for the different exposed areas. Dark currents are represented as dashed lines. -Fig1b.txt : Chronoamperometry plot measured by back illumination in 0.1 M KPi with 0.1 M Na2SO3 for the three exposed areas. Inset:  BiVO4 photoanodes synthetized by electrochemical deposition and thermal evaporation.  The area was delimited using an epoxy resin. -Fig1c.txt : Average of current–voltage (J–V) plots measured by back illumination in 0.1 M KPi with 0.1 M Na2SO3 for an equal to exposed area of 1 cm2 (black), 0.2 cm2 (green) and a photoanode of 1 cm2 with a reduced exposed area of 0.2 cm2 (blue).  ### Figure 2 -Fig2a.txt : Charge-transfer resistance (Rct) as a function of applied potential extracted from IS. -Fig2b.txt : Capacitance as a function of applied potential extracted from IS. -Fig2c.txt : Series Resistance (Rc) as a function of the applied potential extracted from IS. -Fig2d.txt : Density of surface states (DOS) as a function of applied potential extracted from IS. -Fig2e.txt : IR-chopped chronoamperometry measurements at 1.2 V vs RHE. -Fig2f.txt : Mobility of electrons (blue), diffusion resistance (green) and recombination resistance (red) as function of the exposed area extracted from the fitting of IMPS, IMVS and IMVS. ### Figure S3 -FigS3a.txt : Current–voltage (J–V) plots measured in 0.1 M KPi (red) and 0.1 M KPi with 0.1 M Na2SO3 (blue). -FigS3b.txt : Current–voltage (J–V) plots measured by front illumination (light blue) and back illumination (dark blue) in 0.1 M KPi with 0.1 M Na2SO3. ### Figure S4 -FigS4a.txt : Incident-photon to current efficiency (IPCE) under back illumination measured and 0.1 M KPi with 0.1 M Na2SO3. -FigS4b.txt : optical absorbance  of the BiVO4 photoanode and its obtained bandgap (2.47 eV) extracted from the Tauc plot for a indirect transition. ###Figure S5 -FigS5a.txt : Raman spectra for the 0.2 cm2 exposed area before measuring. Colours represent different spots measured in the same sample. -FigS5b.txt : Raman spectra for the 0.4 cm2 exposed area before measuring. Colours represent different spots measured in the same sample. -FigS5c.txt : Raman spectra for the 1 cm2 exposed area before measuring. Colours represent different spots measured in the same sample. -FigS5d.txt : Raman spectra for the 0.2 cm2 exposed area after measuring. Colours represent different spots measured in the same sample. -FigS5e.txt : Raman spectra for the 0.4 cm2 exposed area after measuring. Colours represent different spots measured in the same sample. -FigS5f.txt : Raman spectra for the 1 cm2 exposed area after measuring. Colours represent different spots measured in the same sample.

ShareScore

36/100

Overall dataset sharing score

Score breakdown

These five areas show where the dataset supports — or may limit — practical reuse.

Stewardship: 4
Harmonization: 4
Access: 16
Reuse readiness: 8
Engagement: 4