Solution Phase Growth and Analysis of Super-thin Zigzag Tin Selenide Nanoribbons

<p>Tin selenide (SnSe), a highly promising layered material, has been garnering particular interest in recent times due to its significant promise for future energy devices. Herein we report a simple solution-phase approach for growing highly crystalline layered SnSe nanoribbons. Polyvinylpyrrolidone (PVP) was used as a templating agent to selectively passivates the (100) and (001) facets of the SnSe nanoribbons resulting in the unique growth of nanoribbons along their&nbsp;<em>b</em>-axis with a defined zigzag edge state along the sidewalls. The SnSe nanoribbons are few layers thick (&sim;20 layers), with mean widths of &sim;40 nm, and achievable length of&nbsp;&gt;1&nbsp;<em>&mu;</em>m. Nanoribbons could be produced in relatively high quantities (&gt;150 mg) in a single batch experiment. The PVP coating also offers some resistance to oxidation, with the removal of the PVP seen to lead to the formation of a SnSe/SnO<em>_x</em>&nbsp;core-shell structure. The use of non-toxic PVP to replace toxic amines that are typically employed for other 1D forms of SnSe is a significant advantage for sustainable and environmentally friendly applications. Heat transport properties of the SnSe nanoribbons, derived from power-dependent Raman spectroscopy, demonstrate the potential of SnSe nanoribbons as thermoelectric material.</p>