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Role of Benzylic Deprotonation in Nickel-Catalyzed Benzylic Dehydrogenation

<p>Alkylarenes are readily functionalized via the corresponding&nbsp;benzylic anions. Benzylic anions have been used for a range of catalytic&nbsp;reactions, including Ni-catalyzed dehydrogenation. Interestingly, the&nbsp;employment of Zn(TMP)2 for slow and incomplete deprotonation of the&nbsp;benzylic position was observed. This manuscript describes a preliminary&nbsp;investigation into the deprotonation of heteroarenes and its relationship to Ni-catalyzed benzylic dehydrogenation.<br> &nbsp;</p>

ShareScore

28/100

Overall dataset sharing score

Score breakdown

These five areas show where the dataset supports — or may limit — practical reuse.

Stewardship
4
Harmonization
4
Access
16
Reuse readiness
4
Engagement
0

Dataset details

Repository
zenodo
Published
July 8, 2021
License
cc-by-4.0
DOI
10.5281/zenodo.5088176

Scored with release 0.9.0

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