Fig. 3 in Catalysis by allene oxide synthases (CYP74A and CYP74C): Alterations by the Phe/Leu mutation at the SRS-1 region

Fig. 3. Products (Me/TMS) of 9(S)-HPOD (A and B) and 13(S)-HPOD (C and D) conversions by recombinant WT LeAOS3 (А and C) and LeAOS F108L mutant form (B and D). 1a and 1b, threo and erythro isomers of 9,10-dihydroxy-12- octadecenoic acid; 3, 10-hydroxyphytonoic acid; 4, 9,10-epoxy-11-hydroxy-12- octadecenoic acid; 6a and 6b, threo and erythro isomers of 12,13-dihydroxy-9- octadecenoic acid; 8, 11-hydroxy-12,13-epoxy-9-octadecenoic acid; 10, 9-hydroxy-12,13-epoxy-10-octadecenoic acid. The structural formulae of products are presented in Fig. 2. 9-HOD, (9S,10E,12Z)-9-hydroxy-10,12-octadecadienoic acid.