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Figure 4 from: Zaliska O, Stasiv K, Maksymovych N, Hrynkiv Y (2020) The trends of assisted reproductive technologies and cost for ovarian stimulation protocols in Ukraine. Pharmacia 67(4): 269-276. https://doi.org/10.3897/pharmacia.67.e55159
Figure 4 Dynamics of the cost of оvarian stimulation protocols (ovarian stimulation) in 2015, 2020.
Electrooculography-based continuous eye-writing recognition system for efficient assistive communication systems
<p>All the original continuous EOG data of participant 001, 002, and 003 used in the experiments are contained in this database.</p>
Data from: DNA methylation and gene expression changes derived from assisted reproductive technologies can be decreased by reproductive fluids
The number of children born since the origin of Assisted Reproductive Technologies (ART) exceeds 5 million. The majority seem healthy, but a higher frequency of defects has been reported among ART-conceived infants, suggesting an epigenetic cost. We report the first whole-genome DNA methylation datasets from single pig blastocysts showing differences between in vivo and in vitro produced embryos. Blastocysts were produced in vitro either without (C-IVF) or in the presence of natural reproductive fluids (Natur-IVF). Natur-IVF embryos were of higher quality than C-IVF in terms of cell number and hatching ability to. RNA-Seq and DNA methylation analyses showed that Natur-IVF embryos have expression and methylation patterns closer to in vivo blastocysts. Genes involved in reprogramming, imprinting and development were affected by culture, with fewer aberrations in Natur-IVF embryos. Methylation analysis detected methylated changes in C-IVF, but not in Natur-IVF, at genes whose methylation could be critical, such as IGF2R and NNAT.
DFT-predicted equilibrium structures of Ir(III) complexes for halogen bond-assisted chemo-sensors
<p>Fully relaxed equilibrium structures of <strong>IrF-XB</strong> (without chloride anion coordinated by halogen bonding) as well as <strong>IrF-XBCl</strong> (with chloride anion coordinated by halogen bonding), <strong>IrF-XBBr</strong>, <strong>IrF-XB-Acetate</strong> and <strong>(IrF-XB)2-Acetate</strong> as predicted at the DFT level of theory (B3LYP/def2-SVP) including D3BJ dispersion correction and implicit solvent effects (acetonitrile). All investigated Ir(III)-based molecular sensors were optimized in singlet and triplet multiplicity in order to (subsequently) evaluate the Franck-Condon photophysics as well as the properties of the emissive triplet state. The multiplicity is indicated in the filename.</p>
Scheme 4 from: Mateev E, Irfan A, Mateeva A, Georgieva M, Zlatkov A (2024) Microwave-assisted organic synthesis of pyrroles (Review). Pharmacia 71: 1-10. https://doi.org/10.3897/pharmacia.71.e119866
Scheme 4 Microwave irradiated condensation of diketone with primary amine.
Scheme 1 from: Mateev E, Irfan A, Mateeva A, Georgieva M, Zlatkov A (2024) Microwave-assisted organic synthesis of pyrroles (Review). Pharmacia 71: 1-10. https://doi.org/10.3897/pharmacia.71.e119866
Scheme 1 General Paal-Knorr synthesis of pyrroles.
Figure 4 from: Mateev E, Irfan A, Mateeva A, Georgieva M, Zlatkov A (2024) Microwave-assisted organic synthesis of pyrroles (Review). Pharmacia 71: 1-10. https://doi.org/10.3897/pharmacia.71.e119866
Figure 4 Chemical reactions of the pyrrole.
Scheme 22 from: Mateev E, Irfan A, Mateeva A, Georgieva M, Zlatkov A (2024) Microwave-assisted organic synthesis of pyrroles (Review). Pharmacia 71: 1-10. https://doi.org/10.3897/pharmacia.71.e119866
Scheme 22 Synthesis of N-substituted pyrrole derivatives with nanocatalysts or MW.
Scheme 11 from: Mateev E, Irfan A, Mateeva A, Georgieva M, Zlatkov A (2024) Microwave-assisted organic synthesis of pyrroles (Review). Pharmacia 71: 1-10. https://doi.org/10.3897/pharmacia.71.e119866
Scheme 11 Microwave-Assisted Sila-Stetter/Paal-Knorr Reaction
Scheme 18 from: Mateev E, Irfan A, Mateeva A, Georgieva M, Zlatkov A (2024) Microwave-assisted organic synthesis of pyrroles (Review). Pharmacia 71: 1-10. https://doi.org/10.3897/pharmacia.71.e119866
Scheme 18 Clauson-Kaas synthesis of pyrroles catalyzed by [hmim][HSO4].
Figure 1 from: Mateev E, Irfan A, Mateeva A, Georgieva M, Zlatkov A (2024) Microwave-assisted organic synthesis of pyrroles (Review). Pharmacia 71: 1-10. https://doi.org/10.3897/pharmacia.71.e119866
Figure 1 Electromagnetic spectrum.
Scheme 10 from: Mateev E, Irfan A, Mateeva A, Georgieva M, Zlatkov A (2024) Microwave-assisted organic synthesis of pyrroles (Review). Pharmacia 71: 1-10. https://doi.org/10.3897/pharmacia.71.e119866
Scheme 10 Nano-organocatalyst promoted Paal-Knorr reaction.
Scheme 14 from: Mateev E, Irfan A, Mateeva A, Georgieva M, Zlatkov A (2024) Microwave-assisted organic synthesis of pyrroles (Review). Pharmacia 71: 1-10. https://doi.org/10.3897/pharmacia.71.e119866
Scheme 14 Paal-Knorr MW synthesis in the presence of alkaline salts as catalysts.
Scheme 25 from: Mateev E, Irfan A, Mateeva A, Georgieva M, Zlatkov A (2024) Microwave-assisted organic synthesis of pyrroles (Review). Pharmacia 71: 1-10. https://doi.org/10.3897/pharmacia.71.e119866
Scheme 25 MW assisted synthesis of 1,2-disubstituted pyrroles on the surface of silica gel.
Scheme 17 from: Mateev E, Irfan A, Mateeva A, Georgieva M, Zlatkov A (2024) Microwave-assisted organic synthesis of pyrroles (Review). Pharmacia 71: 1-10. https://doi.org/10.3897/pharmacia.71.e119866
Scheme 17 Synthesis of 2-pyrrolin-5-ones by Hantzsch-type reaction.
Scheme 24 from: Mateev E, Irfan A, Mateeva A, Georgieva M, Zlatkov A (2024) Microwave-assisted organic synthesis of pyrroles (Review). Pharmacia 71: 1-10. https://doi.org/10.3897/pharmacia.71.e119866
Scheme 24 MW irradiated synthesis of functionalized pyrroles using UO2(NO3).6H2O as a catalyst.
Scheme 7 from: Mateev E, Irfan A, Mateeva A, Georgieva M, Zlatkov A (2024) Microwave-assisted organic synthesis of pyrroles (Review). Pharmacia 71: 1-10. https://doi.org/10.3897/pharmacia.71.e119866
Scheme 7 MW synthesis of pyrroles from diketons and acetic acid.
Figure 2 from: Mateev E, Irfan A, Mateeva A, Georgieva M, Zlatkov A (2024) Microwave-assisted organic synthesis of pyrroles (Review). Pharmacia 71: 1-10. https://doi.org/10.3897/pharmacia.71.e119866
Figure 2 Major advantages of MW assisted synthesis.
Scheme 16 from: Mateev E, Irfan A, Mateeva A, Georgieva M, Zlatkov A (2024) Microwave-assisted organic synthesis of pyrroles (Review). Pharmacia 71: 1-10. https://doi.org/10.3897/pharmacia.71.e119866
Scheme 16 Solvent-free MW synthesis of pyrroles with organocatalyst.
Scheme 21 from: Mateev E, Irfan A, Mateeva A, Georgieva M, Zlatkov A (2024) Microwave-assisted organic synthesis of pyrroles (Review). Pharmacia 71: 1-10. https://doi.org/10.3897/pharmacia.71.e119866
Scheme 21 Solvent-free synthesis of novel sulfonylpyrroles by MW heating.
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Allen Brain Atlas
Allen Brain Atlas is an Allen Institute collection of brain map atlases, datasets, APIs, and analysis tools covering mouse, human, and non-human primate brain resources.
Annotated Behaviour and Observability Dataset (ABODe)
ABODe is a University of Edinburgh DataShare dataset for behavior classification in group-housed mice using home-cage video, identities, bounding boxes, ground-plate positions, and annotator labels.
DANDI Archive for NWB datasets
DANDI is a BRAIN Initiative archive for publishing and sharing neurophysiology data, including electrophysiology, optophysiology, and behavioral data packaged as NWB and related standards.
International Brain Laboratory public data
The International Brain Laboratory public data releases expose standardized mouse decision-making experiments, including Neuropixels recordings, widefield calcium imaging, behavior, and session metadata accessed through the ONE API.
OpenNeuro
OpenNeuro is a free, open platform for sharing neuroimaging datasets, with public search, dataset pages, and download paths for web, S3, DataLad, and the OpenNeuro CLI.