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1,341 results for “isotopes”
Supplementary Data to Kinetic oxygen isotope fractionation between water and aqueous OH- during hydroxylation of CO2
<p>In this dataset, we provide analytical data to <strong>Kinetic oxygen isotope fractionation between water and aqueous OH<sup>-</sup> during hydroxylation of CO<sub>2</sub></strong> by Bajnai and Herwartz (2021). Also deposited here is the R code that was used to generate the figures in the manuscript.</p>
SIA-BRA: The carbon and nitrogen stable isotope ratios of animals of Brazilian biomes and coastal marine areas
<p>SIA-BRA is a compilation of C and N stable isotope ratios of terrestrial and aquatic animals sampled in Brazilian biomes and coastal-marine areas.</p> <p>Version 1.0 contains isotopic data of c. 21,804 non-captive wildlife specimens, excluding livestock production or laboratory<br> experiments. They were 13,881 vertebrates and 7,923 invertebrates. There are 11 phyla, with a clear dominance of Chordata (64%) and Arthropoda (29%), 36 classes, 154 orders, 473 families, 894 genera and 1,157 species.</p> <p>They were divided into the following habitats: terrestrial (30% of the total), freshwater (27%), oceanic (40%)<br> and estuarine (4%) (see <a href="https://doi.org/10.1111/geb.13449">https://doi.org/10.1111/geb.13449</a>)</p> <p>Software format: Data are supplied as delimited text files (.csv).</p>
Shelf–to–basin shuttle of highly fractionated chromium isotopes in the Arctic Ocean
<p>This dataset contains total dissolved chromium concentration and isotopic ratios in seawater associated with our paper "Shelf–to–basin shuttle of highly fractionated chromium isotopes in the Arctic Ocean" (submitted and accepted in Geochimica Cosmochimica Acta).</p> <p>The seawater samples were collected during the 2015 ArcticNet/Geotraces cruise aboard the CCGS Amundsen along the sections GN02 and GN03. </p> <p>All processing and measurements were done at the Saskatchewan Isotope Laboratory at the University of Saskatchewan (Canada).</p> <p>This data will also be available in the next GEOTRACES Intermediate Data Product (November 2025).</p> <p><span><strong>></strong> Cr_53_52_D_DELTA_BOTTLE_METADATA-2015CanadianArcticGEOTRACEScruise_OVERVIEW.csv : details the context of the expedition and the sampling/processing methods;</span></p> <p><span><strong>></strong> Cr_53_52_D_DELTA_BOTTLE_METADATA-2015CanadianArcticGEOTRACEScruise_DATA.csv : gives details on the data (<em>e.g.</em> units), as well as technical information associated with the measurements;</span></p> <p><span><strong>></strong> Cr_53_52_D_DELTA_BOTTLE_DATA-2015CanadianArcticGEOTRACEScruise.csv : chromium data associated with the paper.</span></p>
Stable isotope ratios of C, N and S in Southern Ocean sea stars (1985-2017)
<p>Sea stars (Echinodermata: Asteroidea) are a key component of Southern Ocean benthos, with 16% of the known sea star species living there. In temperate marine environments, sea stars commonly play an important role in food webs, acting as keystone species. However, trophic ecology and functional role of Southern Ocean sea stars are still poorly known, notably due to the scarcity of large-scale studies. Here, we report 24332 trophic marker (stable isotopes and elemental contents of C, N and S of tegument and/or tube feet) and biometric (arm length, disk radius, arm to disk ratio) measurements in 2456 specimens of sea stars. Samples were collected between 12/01/1985 and 08/10/2017 in numerous locations along the Antarctic littoral and Subantarctic islands. The spatial scope of the dataset covers a significant portion of the Southern Ocean (Latitude: 47.717° South to 86.273° South ; longitude: 127.767° West to 162.201° East ; depth: 6 to 5338 m). The dataset contains 133 distinct taxa, including 72 currently accepted species spanning 51 genera, 20 families and multiple feeding guilds / functional groups (suspension feeders, sediment feeders, omnivores, predators of mobile or sessile prey). For 505 specimens, mitochondrial CO1 genes were sequenced to confirm and/or refine taxonomic identifications, and those sequences are already publicly available through the Barcode of Life Data System. This number will grow in the future, as molecular analyses are still in progress. Overall, thanks to its large taxonomic, spatial, and temporal extent, as well as its integrative nature (combining genetic, morphological and ecological data), this dataset can be of wide interest to Southern Ocean ecologists, invertebrate zoologists, benthic ecologists, and environmental managers dealing with associated areas.</p>
Monthly climate variables of isotope-enabled climate model simulations over the last millennium (850-1849CE) version 2
<p>Here we provide climate fields in monthly resolution for five isotope-enabled model: ECHAM5-wiso (Sjolte et al. 2018, Werner et al. 2016), GISS-E2-R (Lewis and Legrande 2015, Colose et al 2016), iCESM (Brady et al. 2019, Stevenson et al 2019), iHadCM3 (Bühler et al. 2021, Tindall et al. 2009), and isoGSM (Yoshimura et al. 2008) in supplement to Buehler et al. (2021, submitted to Clim. Past. Discuss.). The model simulations were performed with different sets of boundary conditions as described in Bühler et al. (2021, submitted to Clim. Past. Discuss.) in line with the PMIP3 protocoll (Schmidt et al. 2012). We provide output for surface temperature (in K), total precipitation amount (in mm month^-1), evaporation (in mm month^-1), latent heat (in W m^-2), and oxygen isotope ratios of precipitation (in permil).<br> Additionally, we provide simulation output extracted at cave locations within the SISAL v.2. database (https://researchdata.reading.ac.uk/256/, Comas-Bru et al. (2020)). We include output for sites that pass the resolution and dating screening, meaning that have at least 2 radiometric dates (or are lamina-counted) and provide 36 oxygen isotope ratio measurements within the last millennium.</p> <p>For version 2, we updated the damaged ECHAM5 precipitation file and the time axis to the iCESM precipitation and tsurf files.</p>
Water stable isotope, temperature and electrical conductivity dataset (snow, ice, rain, surface water, groundwater) from a high alpine catchment (2019-2021).
<p>Data collected in the Otemma forefield in Switzerland (45°56’03”N,7°24’42”) from July 2019 to October 2021.<br> Data were collected by the research teams of Bettina Schaefli<sup>2</sup> and Stuart N. Lane<sup>1</sup>.</p> <p><sup>1</sup> Institute of Earth Surface Dynamics (IDYST), University of Lausanne, 1015 Lausanne, Switzerland</p> <p><sup>2</sup> Institute of Geography (GIUB), University of Bern, 3012 Bern, Switzerland</p> <p>For further information, please contact:</p> <ul> <li>tom.muller.1@unil.ch</li> </ul> <p><strong>Description of the dataset</strong></p> <p>This dataset contains water stable isotope (δ<sup>2</sup>H, δ<sup>17</sup>O, δ<sup>18</sup>O), water temperature and water electrical conductivity (EC) measurements collected from the Otemma glacier catchment.</p> <p>All water isotope samples were collected directly from the source and stored in 12 mL amber glass vials with an air-tight caps. River samples were first collected with an automatic ISCO 6712 portable water sampler with 1L open plastic bottles and transferred in 12 mL vials every one to two weeks. All isotope analysis were performed using a Wavelength-Scanned Cavity Ring Down Spectrometer (Picarro 2140-I, Santa Clara, California, USA) and expressed relative to the international Vienna Standard Mean Ocean Water (VSMOW) standards.</p> <p>All EC and water temperature measurements were performed with a WTW Multi 3510 IDS logger with a IDS TetraCon® 925 probe.</p> <p>The dataset contains measurements performed at various locations within the catchment. A total of approximately 1500 measurements are provided. In the dataset each point correspond to a measurement station (column "<strong>Station</strong>") which we classified in specific class of water (column "<strong>Type</strong>") as follows :</p> <ul> <li><strong>Stream </strong>: samples collected at three locations, from the glacier snout, after a small outwash plain and 2km downstream.</li> <li><strong>Tributary </strong>: 5 hillslopes tributaries originating from small seasonal overland flow or small springs at the base of the morainic hillslope. Those tributaries were monitored weekly. In addition, a few other seasonal lateral streams were sampled in various locations (Type: Other tributaries).</li> <li><strong>Bedrock </strong>: A few exfiltrations directly leaking out of the bedrock outcrop were sampled.</li> <li><strong>Ice </strong>: Ice was sampled either as surface ice (small cores 5 cm deep), as deeper cores (5 to 8m deep) or as meltwater from supraglacial gullies. All solid ice samples were melted at ambiant air temperature in air-tight plastic bags before being transferred into 12 mL vials.</li> <li><strong>Snow </strong>: The snowpack was sampled either at the surface (0 to 5cm) or at about 20 cm depth. Where possible, meltwater leaking from the snowpack was sampled. At 3 locations in 2021, we dug snowpits from which we sampled snow at different layers with depth. All solid snow samples were melted at ambiant air temperature in air-tight plastic bags before being transferred into 12 mL vials</li> <li><strong>Rain </strong>: Rainwater was mostly sampled at our camp site at 2450 m. asl. Rainwater samples represent single rain events which are identified by dry periods of at least one day long.</li> <li><strong>Groundwater </strong>: shallow (2 to 3 meters) fully-screened groundwater wells were installed in the outwash plain and water sampled monthly in the snow-free season.</li> </ul> <p>- GPS coordinates are provided with each point (Swiss coordinate system CH1903+ / LV95<strong> (EPSG: 2056)).</strong></p> <p>- Dates are provided in local timezone (GMT+1 with daylight saving time) and in UTC date format.</p> <p>- Analyitcal error from the Picarro spectrometer is reported as 1 standard deviation.</p> <p>More information can be accessed in the corresponding publication by Müller et al. (to be published in 2023).</p> <p><strong>Data files</strong></p> <ul> <li><em>Otemma_isotope_EC_T_2019_2021.csv</em> : file containing all data with GPS coordinates</li> <li> <p><em>isotope_locations_Otemma.jpg</em> : an overview of the locations of each measurement point</p> </li> <li> <p><em>Otemma_Isotopes_2019-2020.html </em>: interactive plots of all datasets (δ<sup>2</sup>H, EC, temperature), classified by Type.</p> </li> </ul>
Identification of microbial exopolymer producers in sandy and muddy intertidal sediments by compound-specific isotope analysis.
<p>This dataset supports the version 2 of the paper entitled <em>Identification of microbial exopolymer producers in sandy and muddy intertidal sediments by compound-specific isotope analysis :</em></p> <p><em>Hubas, Cédric; Gaubert-Boussarie, Julie; D’Hondt, An-Sofie; Jesus, Bruno; Lamy, Dominique; Meleder, Vona; Prins, Antoine; Rosa, Philippe; Stock, Willem; Sabbe, Koen. Identification of microbial exopolymer producers in sandy and muddy intertidal sediments by compound-specific isotope analysis. Peer Community Journal, Volume 3 (2023), article no. e104. doi : <a href="https://doi.org/10.24072/pcjournal.336">10.24072/pcjournal.336</a>. <a href="https://peercommunityjournal.org/articles/10.24072/pcjournal.336/">https://peercommunityjournal.org/articles/10.24072/pcjournal.336/</a></em></p>
Time series of stable water isotopes (d18O, d2H) from Carvins Cove Reservoir in Southwestern Virginia, USA 2024-2025
Samples of stable water isotopes (delta 18O and delta 2H) were collected from surface waters and depth profiles in Carvins Cove Reservoir (Roanoke, Virginia, USA). Carvins Cove Reservoir is owned operated by the Western Virginia Water Authority as a primary drinking water source for Roanoke, Virginia. Samples were collected approximately monthly at two sites along a primary tributary and depth profiles at multiple transects within Carvins Cove Reservoir from May 2024 - April 2025. Additional isotope samples were analyzed from precipitation collected at the Carvins Cove Reservoir dam in 2024. Samples were analyzed using cavity ringdown spectroscopy and reported as deviation of concentration from that of Vienna standard mean ocean water. An Rmarkdown file to visualize the dataset accompanies the package.
Dust geochemistry and lead isotopes along an urban-rural transect in central Ohio, 2021
This data package contains geochemical concentrations and stable lead isotope ratios for dust samples collected along an urban-rural land use gradient in central Ohio during 2021. The purpose of the study was to characterize the geochemical and isotopic signatures of dust in relation to different land uses, to see how much dust varies across land use and by season. At four sites along an urban-rural transect in central Ohio, we collected weekly bulk deposition samples and analyzed the geochemical composition (47 elements including major elements, trace metals, and rare earth elements) and stable lead isotopes (208Pb, 207Pb, 206Pb, and 204Pb) of the particulate matter. This study demonstrates the tight connection between land use and anthropogenic dust composition in a region where land use is changing rapidly as development encroaches into farmland. This dataset is complete and will not be updated.
Nitrogen and carbon concentrations and stable isotope ratios (δ¹⁵N and δ¹³C) in European moss samples, 2005-2006
This dataset contains nitrogen (N) and carbon (C) concentrations and stable isotope ratios (δ¹⁵N and δ¹³C) measured in moss samples collected across Europe within the framework of the ICP Vegetation programme (International Cooperative Programme on Effects of Air Pollution on Natural Vegetation and Crops, UNECE LRTAP Convention). Moss surveys are conducted every five years and the data presented here correspond specifically to the first sampling campaign, carried out in 2005/2006. During the 2005/2006 European moss survey, approximately 3,000 moss samples were collected at non-urban and semi-natural sites across 16 European countries following a standardized biomonitoring protocol. The dataset used in this study comprises a subset of 1,022 moss samples (approximately 35 % of the total survey), provided by 12 European countries, which were selected for the determination of nitrogen and carbon concentrations and their corresponding stable isotope signatures (δ¹⁵N and δ¹³C). Moss samples collected by each participating country were sent to the Integrated Environmental Quality Laboratory (LICA), Institute for Biodiversity and Environment (BIOMA - University of Navarra), where all chemical and isotopic analyses were subsequently performed under uniform analytical conditions. In addition, this dataset incorporates moss data from Sweden, Croatia and Macedonia for the same sampling year, which were not included in the official ICP Vegetation 2005/2006 dataset. The European moss biomonitoring network was established to provide a complementary, high spatial resolution and time-integrated measure of atmospheric deposition of nitrogen and other pollutants within terrestrial ecosystems. The approach is based on the ability of ectohydric mosses to accumulate nutrients and trace elements directly from wet and dry atmospheric deposition, enabling dense spatial sampling across large geographical areas. This biomonitoring framework supports the assessment of spatial patterns of atmos
Gross methane production and consumption estimated for intact soil cores from agricultural plots including environmental covariates and example raw isotope pool dilution data
This study was performed to determine how different soil moistures, soil sources, and agricultural practices affected the gross CH4 fluxes (i.e., rates of methanogenesis) of soils. We extracted intact soil cores from two agricultural sites in the USA in row crop plots under conventional, no-till, and organic management. We then took them to the lab, manipulated their moisture levels, incubated them at room temperature for 22 weeks, and measured gas fluxes at weeks 6 and 21. We developed and utilized a new form of CH4 isotope pool dilution (IPD) to estimate gross CH4 production and consumption fluxes. This new method can measure IPD in a bag headspace that loses volume over time due to sampling. We fit the IPD model to the data and extracted gross CH4 production (P) and consumption (K) constants. These along with calculated fluxes and covariates measured (e.g., moisture, inorganic N) are reported in the main data table.
Stable carbon and oxygen isotopes in tree rings and basal area increment from mature temperate forests within the AmeriFlux network.
Data were used to investigate long-term changes in tree intrinsic water use efficiency (iWUE, i.e., the ratio between CO2 assimilation and stomatal conductance) and the underlying physiological mechanisms. We used delta18O to estimate the 18O enrichment in leaf water above the source water, Delta18OLW. Moreover we assessed the relationship between isotope-derived parameters and atmospheric CO2 (ca) and climate factors. Isotope-related parameters included in the dataset are: alpha-cellulose delta13C, carbon isotope discrimination (Delta13C), intercellular CO2 concentration (ci) and the ratio of intercellular to atmospheric CO2 concentrations (ci/ca), alpha-cellulose delta18O, estimated delta18O in precipitation (see Method), oxygen isotope discrimination above the source water (Delta18O). The dataset includes also the following climate parameters: growing season temperature (Tgrs), precipitation (Pgrs) and vapor pressure deficit (VPDgrs) and mean annual temperature (Ta), precipitation (Pa) and vapor pressure deficit (VPDa), and standard precipitation-evaporation index relative to August, with 3 months lag (SPEI8_3) from the global database. Finally, we also include the ca values that were used to calculate delta13C, iWUE and ci/ca. All the equations used to calculate the isotope-derived parameters, including the leaf water Delta18O (see Figure 3 in Guerrieri et al. 2019 PNAS) are also provided.
Marcell Experimental Forest stable isotopes of water, 2008 - ongoing
This data set reports natural abundance water stable isotope values (deuterium and oxygen-18) from the Marcell Experimental Forest (MEF) in Itasca County, Minnesota. Samples of precipitation, snowpack, stream, bog, lagg, soil water, upland runoff, lake water and aquifer groundwater have been collected since 2008 for chemistry measurement. Sampling is ongoing. The samples originate from multiple research plots and catchments, with many of the samples collected as part of the Spruce and Peatland Responses Under Changing Environments (SPRUCE) experiment. Water isotopes have been measured for some but not all samples. More values from more sites will be added as the archive of water samples is analyzed for water isotopes. The MEF is operated, maintained, and funded by the USDA Forest Service, Northern Research Station. The SPRUCE experiment is a multi-year cooperative project among scientists of the Oak Ridge National Laboratory operated by UT-Battelle, LLC and the USDA Forest Service, Northern Research Station, with funding from the US Department of Energy, Biological and Environmental Research Program
Oxygen-18 isotope ratios, chemistry, and tracers in storm water from WS10 hillslope experiment in the HJ Andrews Experimental Forest, 2001-2003
Oxygen-18 ratios, expressed as Delta-18O or D18O (parts per hundred), measured in WS10 discharge and WS10 precipitation. The time series spans from January 2001 to February 2003, period during which precipitation and streamflow were sampled mostly manually and weekly. The time series also includes some periods of higher frequency automatic sampling in streamflow and precipitation in winter 2001 and winter 2002. The precipitation Delta-18O time series corresponds to the Delta-18O measured at PRIMET station located about 1 km from WS10 outlet at a similar altitude, except from 01-Sep-2002 to 04-Feb-2003, when the Delta-18O of precipitation sampled sequentially on an experimental hillslope of WS10, was used (the collector was located on the south aspect, 91 m upstream from the outlet).
Accession numbers for radiocarbon and stable carbon isotopes of dissolved organic carbon (DOC) and dissolved inorganic carbon (DIC) in soil leachates from permafrost soils collected from the North Slope of Alaska in the summers of 2018 and 2022
Leachates of dissolved organic carbon (DOC) from permafrost soils were prepared from soils collected from the North Slope of Alaska in 2018 and 2022. Soil leachates were then either kept in the dark or exposed to light from LEDs at 305 nm (UV) and 405 nm (visible), and then inoculated with native microbial communities and incubated. At the start of the biological incubations, single replicates of the DOC after dark or light treatment and inoculation were assigned accession numbers and analyzed for 14C and 13C at the National Ocean Sciences Accelerator Mass Spectrometry (NOSAMS) facility. At the end of the biological incubations, duplicates of the dissolved inorganic carbon (DIC) in those waters were assigned accession numbers and analyzed for 14C and 13C at the NOSAMS facility.
Radiocarbon and stable carbon isotopes of carbon dioxide produced by respiration of dissolved organic carbon (DOC) leached from permafrost soils collected from the North Slope of Alaska in the summers of 2018 and 2022
Dissolved organic carbon (DOC) was leached from permafrost soils near the Toolik Field Station in the Alaskan Arctic, either kept in the dark or exposed to light treatments, and then incubated with native permafrost microbial communities. The radiocarbon (14C) and stable carbon (13C) isotopic compositions of the initial DOC present in the dark or light-exposed permafrost soil leachates and the carbon dioxide (CO2) produced by microbial respiration of dark or light-exposed permafrost DOC were quantified.
Data from nitrogen isotopic analyses used to calculate biological nitrogen fixation (BNF) rates and field measurements from lichen, bryophyte, litter, and soil samples in MAT2006 plots, Arctic LTER, Toolik Field Station, Alaska, summers 2022-2023.
This dataset contains nitrogen (N) fixation and isotope data from experimental samples collected at Toolik Lake, Alaska during the 2022 and 2023 growing seasons. Sampling was conducted across multiple block treatments to capture spatial variability and included four substrate types: lichen, moss, litter, and soil. Within each plot, substrates were collected systematically along transects to ensure representative sampling, with lichen samples collected opportunistically due to lower abundance. Samples were incubated in the field under ambient conditions using 15N₂ to measure biological nitrogen fixation (BNF). In 2023, a short-term wetting experiment was conducted to assess the influence of moisture on BNF rates, with subsamples exposed to controlled additions of water. Across both years, data include isotope ratios, incubation conditions, moisture, fresh and dry biomass, and treatment assignments. The dataset provides information on BNF across substrate types, moisture regimes, and fertilization treatments in Arctic tundra. These data support investigation of N cycling processes, the influence of moisture and fertilization on fixation rates, and variability across vegetation types. The dataset is complete for the two field seasons (2022 and 2023) and includes sample- and block-level metadata necessary for reuse in ecological and biogeochemical research.
Concentration of dissolved inorganic carbon (DIC) and del 13C isotope value for lakes and rivers on North Slope from Brooks Range to Prudhoe Bay, Arctic LTER 1988 to 1989.
Concentration of dissolved inorganic carbon (DIC) and del 13C isotope value for lakes and rivers on North Slope from Brooks Range to Prudhoe Bay, Arctic LTER 1988 to 1989.
Large shark catches (Drumline), water temperatures, salinities, dissolved oxygen levels, and stable isotope values in the Shark River Slough, Everglades National Park (FCE LTER) from May 2009 to May 2011
This dataset provides information on the catches of large sharks in the Shark River Slough in relation to physical factors including dissolved oxygen, water temperature, salinity, and distance upstream. Analysis of data collected suggest that distance from the Gulf of Mexico and salinity have the largest effects on shark catch rates, with most large sharks being caught at the mouth of the estuary in high salinity waters. This dataset includes all sharks caught on drumline gear, including large coastal species such as bull sharks and lemon sharks, as well as smaller coastal species such as Atlantic sharpnose sharks and blacknose sharks.
Stomach contents and stable isotopes from the aquatic food web in Everglades National Park, Florida, USA, 2018-2019
Stable isotope samples were collected among habitats and between seasons at multiple sites in both Shark River Slough and Taylor Slough of Everglades National Park to represent as much of the aquatic food web as possible. Stomach contents were also recorded for many of the collected vertebrate samples. Sampling occurred between October 2018 and April 2019. These data are a follow up study to the FCE1263 data package (https://portal.edirepository.org/nis/mapbrowse?scope=knb-lter-fce&identifier=1263) following the invasion of several fishes, most notably the African Jewelfish (Rubricatochromis letourneuxi), although there are some differences in habitats sampled and overall spatial coverage. R code for analyses associated with these data are available at https://github.com/pjflood/diet_and_pond_enrichment. Data collection is complete.
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