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12 results for “Atmospheric ions”

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zenodo44/100

Strongly Enhanced Cooperative Surface Propensity of Atmospherically Relevant Organic Molecular Ions in Aqueous Solution - data

<p>Dataset pertaining to the manuscript "Boosting aerosol surface effects: strongly enhanced cooperative surface propensity of atmospherically relevant organic molecular ions in aqueous solution", published in <a href="https://doi.org/10.5194/acp-25-3503-2025">Atmos. Chem. Phys., 25, 3503&ndash;3518, 2025</a>. Using liquid-jet photoelectron spectroscopy, we investigate the surface propensity of various carbonaceous species in aqueous solution. We cover a range of substances relevant to atmospheric climate models. Here we give the data of Fig.s 1-3 of our manuscript in numeric form, and document the underlying photoemission spectra including all relevant metadata.</p> <p>Experimental data are documented in the NeXus format (extension .nxs). For a description see:<br>The NeXus Data Format definition (v2024.02), https://manual.nexusformat.org/index.html<br>NXmpes expansion for FAIRmat data (v.2024.07), https://fairmat-nfdi.github.io/nexus_definitions/classes/contributed_definitions/NXmpes.html<br>NXmpes_liquid expansion to NXmpes (v.2024.07), https://fairmat-nfdi.github.io/nexus_definitions/mpes-liquid/classes/contributed_definitions/NXmpes_liquid.html</p> <p>The following files are provided:<br>'Data Collection_Core.nxs'&nbsp; -&nbsp; Photoemission data, core level spectra<br>'Data Collection_Valence.nxs'<strong>&nbsp;</strong> -&nbsp; Photoemission data, valence spectra</p> <p>Ascii data of figures 1a, 2 and 3:<br>'Figure 1 data.txt'<br>'Figure 2 data.txt'<br>'Figure 3 data.txt'</p> <p>Contact person for questions regarding this data set: Uwe Hergenhahn, uhe@fhi.mpg.de . If you use these data for your scientific work we kindly ask you to send us a copy of your published results.</p> <p>Acknowledgements: We acknowledge DESY (Hamburg, Germany), a member of the Helmholtz Association HGF, for the provision of experimental facilities. Parts of this research were carried out at PETRA III, and we would like to thank Moritz Hoesch and his team for assistance in using beamline P04. Beamtime was allocated for proposal I-20220937 EC. Harmanjot Kaur and Bernd Winter acknowledge the European Research Council (ERC) under the European Union&rsquo;s Horizon 2020 research and innovation program (grant agreement no. 883759, AQUACHIRAL). Stephan Th&uuml;rmer acknowledges support from JSPS KAKENHI (grant no. JP20K15229) and ISHIZUE 2024 of Kyoto University. Florian Trinter acknowledges funding by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) &ndash; project 509471550, Emmy Noether Programme. Florian Trinter and Bernd Winter acknowledge support by the MaxWater initiative of the Max-Planck-Gesellschaft. Olle Bj&ouml;rneholm acknowledges support from the Swedish Research Council (VR) through project 2023-04346 and the Swedish Foundation for International Cooperation in Research and Higher Education (STINT) through project 202100-2932. Ricardo Marinho, Joel Pinheiro, and Arnaldo Naves de Brito acknowledge support from the Swedish&ndash;Brazilian collaboration STINT-CAPES (process no. 88881.465527/2019-01). Arnaldo Naves de Brito acknowledges support from FAPESP (the S&atilde;o Paulo Research Foundation, process no. 2017/11986-5), Shell and ANP (Brazil&rsquo;s National Oil, Natural Gas and Biofuels Agency), and CNPq-Brazil (process no. 401581/2016-0). Harmanjot Kaur and Shirin Gholami acknowledge support by the IMPRS for Elementary Processes in Physical Chemistry.</p> <p>Financial support: This research has been supported by the European Research Council, Horizon Europe (grant no. 883759); the Japan Society for the Promotion of Science (grant no. JP20K15229); the Deutsche Forschungsgemeinschaft (grant no. 509471550); the Vetenskapsr&aring;det (grant no. 2023-04346), the Swedish Foundation for International Cooperation in Research and Higher Education (grant no. 202100-2932); the Funda&ccedil;&atilde;o de Amparo &agrave; Pesquisa do Estado de S&atilde;o Paulo (grant no. 2017/11986- 5); and the Conselho Nacional de Desenvolvimento Cient&iacute;fico e Tecnol&oacute;gico (grant no. 401581/2016-0).</p> <p>Version history:<br>1 - initial release<br>2 - numbering of figures adapted to published version, photoemission data added.</p>

opencc-by-4.0Jul 2024View details →
zenodo36/100

Chemical characterization of atmospheric ions at the High-Alpine station Jungfraujoch (Switzerland)

<p>The ion composition at high-altitude (3454 m a.s.l.) was measured with an Atmospheric<br> Pressure interface Time of Flight mass spectrometer (APi-TOF) during a period of nine<br> months, from August 2013 to April 2014. The negative mass spectra were dominated by the<br> ions of sulfuric, nitric, malonic and methanesulfonic acid (MSA) as well as SO5- . The most<br> prominent positive ion peaks were from amines. The other cations were mainly organic compounds<br> clustered with a nitrogen-containing ion, which could be either NH4+ or an aminium.<br> Occasionally the positive spectra were characterized by groups of compounds each differing<br> by a methylene group. In the negative spectrum, sulfuric acid was always observed during<br> clear sky conditions following the diurnal cycle of sun irradiation. On many occasions we<br> also saw a high signal of sulfuric acid during night time when clusters up to the tetramer<br> were observed. A plausible reason for these events could be evaporation from particles at low<br> relative humidity. A remarkably strong correlation between the signals of SO5- and CH3SO3-<br> was observed for the full measurement period. The presence of these two ions during both<br> the day and the night suggests a non-photochemical channel of formation which is possibly<br> linked to halogen chemistry. Halogenated species, especially Br– and IO3- , were frequently<br> observed in air masses that originated mainly from the Atlantic Ocean and occasionally from<br> continental areas based on back trajectory analyses. We found I2O5 clustered with an ion, a<br> species that was proposed from laboratory and modelling studies. All halogenated ions exhibited<br> an unexpected diurnal behaviour with low values during day time. New particle formation<br> (NPF) events were observed and characterized by 1) highly oxygenated molecules (HOMs) and<br> low sulfuric acid or 2) ammonia-sulfuric acid clusters. We present characteristic spectra for<br> each of these two event types based on 26 nucleation episodes. The mass spectrum of the<br> ammonia-sulfuric acid nucleation event compares very well with laboratory measurements<br> reported from the CLOUD chamber. A source receptor analysis indicates that new particle<br> formation events at the Jungfraujoch take place within a restricted period of time of 24-48<br> hours after air masses have had contact with boundary layer. This time frame appears to be<br> crucial to reach an optimal oxidation state and concentration of organic molecules necessary<br> to facilitate nucleation.</p>

opencc-by-4.0Jan 2017View details →
zenodo36/100

Diurnal evolution of negative atmospheric ions above the boreal forest: From ground level to the free troposphere

<p>The data used in the publication is available for download. The unit of the data can be found in the header of the csv files. Please note, that the mass spectrometer data is in UTC+3 time, the rest of the data in UTC+2 time.</p>

opencc-by-4.0Nov 2021View details →
dryad32/100

Data from: Paleolimnological assessment of wildfire-derived atmospheric deposition of trace metal(loid)s and major ions to subarctic lakes (Northwest Territories, Canada)

<p>Wildfires release terrestrial elements to the atmosphere as aerosols, and these events are becoming more frequent and intense in the Arctic boreal forest as the climate is warming. We quantified the impact of atmospheric deposition of aerosols from local wildfires on metal(loid) fluxes using macroscopic charcoal accumulation rates, historical fire mapping, and element concentrations in <sup>210</sup>Pb‐dated lake sediment from five subarctic lakes with small catchments. Lake sediments showed small but significant increases in fluxes (median = 5–10%) for 22 trace metals, metalloids, or major ions following fire events. The impact of wildfire aerosols on element fluxes was mostly due to short‐term (≤2 years) increasing sedimentation rate (6 ± 41% increase), whereas sediment element concentrations were not strongly impacted. Wildfire‐associated deposition to lake sediments was mainly composed of Ca, Al, Fe, Mg, K, Mn, and Na, which are major constituents of ash from burned biomass, but changes in sediment flux were greatest for Sb, As, Ni, Ba, Mn, Mo, and Sr compared to pre‐disturbance conditions. Compared to anthropogenic sources of pollution, wildfire‐associated atmospheric fluxes of metal contaminants to the lakes (e.g., Hg, Pb, As, Sb, and Cd) were low. This study provides quantitative estimates of wildfire impacts on atmospheric geochemical fluxes to subarctic lakes, which can be used for modeling larger‐scale impacts under changing fire regimes.</p>

opencc-zeroSep 2020View details →
zenodo32/100

Continuous new particle formation in a Mediterranean coastal environment: Insights from atmospheric ions behaviour analysis

<p>data used for:&nbsp;</p> <p><strong><span lang="EN-GB">Continuous new particle formation in a Mediterranean coastal environment: Insights from atmospheric ions behaviour analysis</span></strong></p>

opencc-by-4.0Sep 2024View details →
zenodo32/100

Figure data of "Measurement report: Molecular-level investigation of atmospheric cluster ions at the tropical high-altitude research station Chacaltaya (5240 m a.s.l.) in the Bolivian Andes"

<p>This dataset involves the data that is used for the figures in &quot;Measurement report: Molecular-level investigation of atmospheric cluster ions at the tropical high-altitude research station Chacaltaya (5240 m a.s.l.) in the Bolivian Andes&quot;.</p>

opencc-by-4.0Oct 2022View details →
dryad32/100

Data from: Paleolimnological assessment of wildfire-derived atmospheric deposition of trace metal(loid)s and major ions to subarctic lakes (Northwest Territories, Canada)

Open the record for dataset details and reuse information.

publicSep 2020View details →
zenodo28/100

Measurement Report: The observation of atmospheric HONO by wet-rotating-denuder ion chromatograph in a coastal city: Influencing factors and corrective function

<p>The details are also available upon request from the corresponding author (<a href="mailto:jschen@iue.ac.cn">jschen@iue.ac.cn</a>)</p>

opencc-by-4.0Sep 2023View details →
zenodo24/100

Supplementary data for: "The Venusian atmospheric oxygen ion escape: Extrapolation to the early Solar System"

<p>Supplementary data for paper &quot;The Venusian atmospheric oxygen ion escape: Extrapolation to the early Solar System&quot;, submitted to Journal of Geophysical Research: Planets. See README file for description of the data in each file.</p>

opencc-by-4.0Feb 2020View details →
nasa16/100

Hot Ion Atmospheric Escape Data

This bundle contains collated hot ion atmospheric escape data from multiple published sources

restrictedus-pdMar 2025View details →
zenodo12/100

Experimental dataset: TEMPERATURE DEPENDENCE ON STOCHATIC DYNAMIC DIFFUSION COEFFICIENTS OF HEATED ELECTROSPRAY IONIZATION AND ATMOSPHERIC PRESSURE CHEMICAL IONIZATION MASS SPECTROMETRIC INTENSITIES OF ANALYTE IONS OF CONFIGURATIONALLY LOCKED POLYENES – THEORY AND EXPERIMENT

<p>Experimental dataset of heated electrospray ionization and atmospheric pressure chemical ionization mass spectra of configurationally locked polyenes. The dataset is empirical proof of the validity of our new model equation connecting among the stochatic dynamic diffusion parameter, the temperature and the mass spectrometric measurable variable &#39;intensity&#39; of an observable peak of analyte ion.</p>

restrictedJun 2019View details →
zenodo8/100

Chemical ionization quadrupole mass spectrometer with an electrical discharge ion source for atmospheric trace gas measurement (dataset)

<p>Data from field studies provided in Fig. 6 (CYPHEX), 7 (NOTOMO) and 8 (IBAIRN) of</p> <p>Eger, P. G., Helleis, F., Schuster, G., Phillips, G. J., Lelieveld, J., and Crowley, J. N.: Chemical ionization quadrupole mass spectrometer with an electrical discharge ion source for atmospheric trace gas measurement, Atmos. Meas. Tech., 12, 1935&ndash;1954, https://doi.org/10.5194/amt-12-1935-2019, 2019.</p>

restrictedMar 2019View details →

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