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12 results for “cyclopropanes”
A Counterion-Directed Approach to the Diels-Alder Paradigm: Cascade Synthesis of Tricyclic Fused Cyclopropanes
<p>An approach to the intramolecular Diels–Alder reaction has led to a cascade synthesis of complex carbocycles composed of three fused rings and up to five stereocenters with complete stereocontrol. Computational analysis reveals that the reaction proceeds by a Michael/Michael/cyclopropanation/epimerization cascade in which size and coordination of the counterion is key.</p> <p>This date set contains DFT optimised structures as described in the title paper. </p>
NMR, HPLC and HRMS data - General Cyclopropane Assembly via Enantioselective Transfer of a Redox-Active Carbene to Aliphatic Olefins
<p>Raw data for the article with the same title.</p> <p>ChemRxiv pre-print (<a href="https://doi.org/10.26434/chemrxiv.7436795">https://doi.org/10.26434/chemrxiv.7436795</a>)</p>
SC-XRD - General Cyclopropane Assembly via Enantioselective Transfer of a Redox-Active Carbene to Aliphatic Olefins
<p>Raw data of SC-XRD structures.</p> <p>ChemRxiv pre-print (<a href="https://doi.org/10.26434/chemrxiv.7436795">https://doi.org/10.26434/chemrxiv.7436795</a>)</p> <p> </p>
Enantioselective Assembly of Congested Cyclopropanes using Redox-Active Aryldiazoacetates - NMR, HRMS and X-ray Raw Data
<p>NMR, HRMS and single crystal X-ray diffraction raw data for the compounds in the manuscript ACS Catalysis 2019, DOI: <a href="https://doi.org/10.1021/acscatal.9b02615">https://doi.org/10.1021/acscatal.9b02615</a></p>
Data for article "Triazene-Activated Donor–Acceptor Cyclopropanes: Ring-Opening and (3 + 2) Annulation Reactions"
<p>This upload contains raw data (NMR, X-Ray) files for the article: </p> <p>A. A. Suleymanov, E. Le Du, Z. Dong, B. Muriel, R. Scopelliti, F. Fadaei-Tirani, J. Waser, K. Severin, </p> <p>"Triazene-Activated Donor-Acceptor Cyclopropanes: Ring-Opening and (3 + 2) Annulation Reactions"</p> <p><em>Org. Lett. </em><strong>2020</strong>, DOI: 10.1021/acs.orglett.0c01527<em>.</em></p>
Raw data for the article "Asymmetric Cyclopropanation and Epoxidation via a Catalytically Formed Chiral Auxiliary"
<p>Raw NMR, HPLC, IR and MS data for the article "Asymmetric Cyclopropanation and Epoxidation via a Catalytically Formed Chiral Auxiliary" published in Angewandte Chemie, International Edition, DOI: </p> <p><a href="https://doi.org/10.1002/anie.202113925 ">https://doi.org/10.1002/anie.202113925 </a> </p> <p>The number of the folders correspond to compounds numbers in the article. All details concerning conditions and equipment for measurements can be found in the supporting information of the article.</p>
Primary data for Manuscript provisionally titled Stereoselective access to bioactive cyclopropanes (+)-PPCC and (1R,2S)-2-aminomethyl-1-arylcyclopropane-1-carboxamides from (−)-levoglucosenone
<p><span>Contains HRMS and FID data for compounds described in the manuscript titled, "<span>Stereoselective access to bioactive cyclopropanes (+)-PPCC and (1<em><span>R</span></em>,2<em><span>S</span></em>)-2-aminomethyl-1-arylcyclopropane-1-carboxamides from (−)-levoglucosenone"</span></span></p> <p><span>FIDs can be opened using SpinWorks or Topspin programs.</span></p> <p> </p>
Raw data for the article "Substrate-Controlled C-H or C-C Alkynylation of Cyclopropanes: Generation of Aryl Radical Cations by Direct Light Activation of Hypervalent Iodine Reagents "
<p>Raw computational, NMR, IR and MS data for the article "Substrate-Controlled C-H or C-C Alkynylation of Cyclopropanes: Generation of Aryl Radical Cations by Direct Light Activation of Hypervalent Iodine Reagents " published in Chemical Science, DOI: </p> <p><a href="https://doi.org/10.1039/D2SC04344K">https://doi.org/10.1039/D2SC04344K</a></p> <p>The number of the folders either correspond to compounds numbers in the article or the name of the folder is self-describing. All details concerning conditions and equipment for measurements can be found in the supporting information of the article.</p>
Modular Enantioselective Synthesis of cis-Cyclopropanes through Self-Sensitized Stereoselective Photo-Decarboxylation with Benzothiazolines
<p>Raw data for the characterization of the compounds in the research paper with the same name.</p>
Raw data for the article "Semipinacol Rearrangement of Cyclopropenylcarbinols for the Synthesis of Highly Substituted Cyclopropanes"
<p>Raw NMR, IR and MS data for the article "Semipinacol Rearrangement of Cyclopropenylcarbinols for the Synthesis of Highly Substituted Cyclopropanes" published in Organic Letters, DOI: </p> <p><a href="https://doi.org/10.1021/acs.orglett.3c02543">https://doi.org/10.1021/acs.orglett.3c02543</a></p> <p>The number of the folders either correspond to compounds numbers in the article or the name of the folder is self-describing. All details concerning conditions and equipment for measurements can be found in the supporting information of the article. For convenience, the word file version of the supporting information can be found on the top of the raw data folder.</p>
Presence of Cyclopropane Fatty Acids (CPFA) in Human Plasma
ClinicalTrials.gov study NCT03612700. IPD Sharing: NO. Countries: 1. Publications: 16.
Gene expression comparison of L. reuteri ATCC PTA 6475 and cyclopropane-fatty-acyl-phospholipid synthase mutant
GEO Series GSE24413. Limosilactobacillus reuteri. 6 samples. Type: Expression profiling by array.
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