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101 results for “dissolved organic matter”
Colored dissolved organic matter (CDOM) absorbance from lagoon, ocean, and river sites along the Alaska Beaufort Sea coast, 2021-ongoing
Multiple water types (river, lagoon, ocean) from the North Slope of Alaska and nearshore Beaufort Sea are sampled seasonally by the Beaufort Lagoon Ecosystems LTER (BLE LTER) Core Program to investigate biogeochemical linkages between terrestrial, lagoon, and open ocean ecosystems. Water samples from multiple depths are collected during full ice cover (April), ice break-up (mid-June to early July), and open water (late July and August) periods, filtered, and analyzed for light absorption spectra within 24 hours of collection. Wavelength-specific light absorption coefficients are reported between 250 and 600 nanometers. The data is organized in "long" or "tidy" format, with columns of station, date, wavelength, and absorption. Please see included MakeColumnsAsWavelengths.R, MakeColumnsAsDates.R, and ReshapeDataInExcel.txt for some common ways to reorganize the table for further CDOM analysis. In 2022, data from 2019 were removed due to quality issues (please see revision 1 of this dataset for 2019 CDOM values). For users who may have used 2019 data from this dataset, there are additional files to inform decisions going forward. "BLE_LTER_CDOM_2019_sample_flags.csv" lists which 2019 samples are entirely unreliable, versus usable with caution. "BLE_LTER_CDOM_2021_blank_mean_sd_absorptions.csv" lists mean and standard deviations at each wavelength from all blanks taken in 2021; this is meant to give info on the instruments used and will not be updated further. Please see the methods section for more information on 2019 data.
Composition and biodegradability of dissolved organic matter in supra-permafrost groundwater and surface waters near Simpson Lagoon, Alaska
Supra-permafrost groundwater (SPGW) is an important source of terrestrial dissolved organic matter (DOM) to the Arctic Ocean, yet few studies have investigated the quality or characteristics of this DOM. We sampled fresh SPGW, run-off, and rivers near Simpson Lagoon, Alaska during spring ice break-up (mid-June), summer open water (late July), and fall freeze-up (late September - early October). We measured dissolved organic carbon (DOC) concentrations in these samples and analyzed the composition of DOM using high-resolution mass spectrometry (Fourier transform ion cyclotron resonance mass spectrometry; FT-ICR MS). To measure biodegradable dissolved organic carbon (BDOC), we conducted an aerobic incubation experiment following the methods suggested by Vonk et al. (2015). Briefly, water samples were incubated at 20C for 28 days to measure DOC loss due to remineralization by in-situ microbial communities.
Time series of high-frequency sensor data measuring water temperature, dissolved oxygen, conductivity, specific conductance, total dissolved solids, chlorophyll a, phycocyanin, turbidity, and fluorescent dissolved organic matter at discrete depths in Carvins Cove Reservoir, Virginia, USA in 2020-2025
We monitored water quality in Carvins Cove Reservoir (Roanoke, Virginia, USA; 37.3697 -79.958) with high-frequency (10-minute) sensors in 2020-2025. Carvins Cove Reservoir is owned and managed by the Western Virginia Water Authority as a primary drinking water source. This data package consists of datasets from two separate deployments. First, from July 2020 - August 2021, depth profiles of water temperature were measured on 1-meter intervals using HOBO temperature pendant loggers deployed from 0.1 m below the surface of the reservoir to 10 m depth, and also at 15 and 20 m depth. Additionally, water temperature was measured in the Sawmill Branch inflow at 0.5 m depth using HOBO temperature pendant loggers. Second, from 9 April 2021 - 31 December 2025, depth profiles of water temperature were measured on 1-meter intervals from 0.1 m below the surface of the reservoir to 11 m depth and additionally at 15 and 19 m. A YSI EXO2 sonde measured water temperature, conductivity, specific conductance, chlorophyll a, phycocyanin, total dissolved solids, dissolved oxygen, and fluorescent dissolved organic matter at ~1.5 m depth. A YSI EXO3 sonde measured water temperature, conductivity, specific conductance, total dissolved solids, dissolved oxygen, and fluorescent dissolved organic matter at ~9 m depth, which corresponds to the depth of a water outtake valve. The thermistors, EXO3 sonde, and pressure sensor were deployed at stationary, fixed elevations (referred to as positions) deployed off of the dam near the water outtake valves. Due to variable water levels in the reservoir, the depths of these sensors varied over time. In contrast, the EXO2 was deployed on a buoy from 2021-2022 and remained at 1.5 m depth as the water level fluctuated. However, in 2023, the buoy disappeared in a storm, and after that the EXO2 was deployed at a stationary elevation as the water level fluctuated around the sensor. The EXO2 was redeployed on the buoy in 2024. The monitoring site's maximum de
Time series of high-frequency profiles of depth, temperature, dissolved oxygen, conductivity, specific conductance, chlorophyll a, turbidity, pH, oxidation-reduction potential, photosynthetically active radiation, colored dissolved organic matter, phycocyanin, phycoerythrin, and descent rate for Beaverdam Reservoir, Carvins Cove Reservoir, Falling Creek Reservoir, Gatewood Reservoir, and Spring Hollow Reservoir in southwestern Virginia, USA 2013-2025
Depth profiles of water biogeochemical properties were collected with SeaBird Electronics (SBE) Conductivity, Temperature, and Depth (CTD) profilers from 2013-2025 at five drinking water reservoirs in southwestern Virginia, USA. The study reservoirs are: Beaverdam Reservoir (Vinton, Virginia), Carvins Cove Reservoir (Roanoke, Virginia), Falling Creek Reservoir (Vinton, Virginia), Gatewood Reservoir (Pulaski, Virginia), and Spring Hollow Reservoir (Salem, Virginia). Beaverdam, Carvins Cove, Falling Creek, and Spring Hollow Reservoirs are owned and operated by the Western Virginia Water Authority as primary or secondary drinking water sources for Roanoke, Virginia, and Gatewood Reservoir is a drinking water source for the town of Pulaski, Virginia. The dataset consists of CTD depth profiles measured at the deepest site of each reservoir adjacent to the dam as well as other upstream reservoir sites. The profiles were collected approximately fortnightly in the spring months, weekly in the summer and early autumn, and monthly in the late autumn and winter. Beaverdam Reservoir, Carvins Cove Reservoir, and Falling Creek Reservoir were sampled every year in the dataset (2013-2025); Spring Hollow Reservoir was only sampled 2013-2017 and 2019; and Gatewood Reservoir was only sampled in 2016. Data availability differs across years due to additional sensors that have been added or replaced over time. From 2013-2016, profiles were taken with a CTD equipped with an SBE 43 Dissolved Oxygen sensor and an ECO FLNTU sensor for turbidity and chlorophyll. From 2017-2025, profiles were taken with a CTD equipped with an SBE 43 Dissolved Oxygen sensor, an ECO FLNTU sensor for turbidity and chlorophyll, a PAR-LOG ICSW sensor for photosynthetically active radiation, and a SBE 27 pH and ORP (oxidation-reduction potential) sensor. In 2022 and 2023, profiles were also taken with an additional CTD equipped with an SBE 43 Dissolved Oxygen sensor; an ECO Triplet Scattering Fluorescence sensor for
Soil dissolved organic matter and greenhouse gas fluxes from intact Delmarva Bay wetland soil cores during laboratory simulation of groundwater level rise
Wetlands in low-relief landscapes have dynamic terrestrial-aquatic interfaces as surface water and groundwater levels fluctuate seasonally and these variable water levels influence wetland carbon cycling. Seasonal changes in groundwater levels determine which soils are hydrologically connected to the wetland surface water-groundwater continuum and therefore which soils act as carbon sources. To quantify groundwater-mediated soil dissolved organic matter (DOM) and greenhouse gas (CO2 and CH4) fluxes, we performed a laboratory simulation of groundwater rise on intact soil cores. Soil cores were collected from four Delmarva Bay wetlands located in the low-relief landscape of the Delmarva Peninsula in the Mid-Atlantic United States. At each wetland, two cores (length = 60 cm, diameter = 10.2 cm) were collected: one from within the wetland basin and the second from the transitional zone near the edge of the wetland basin (total number of cores collected = 8). To characterize seasonal hydrologic conditions at each wetland site where intact soil cores were collected (e.g., mean water level, number of saturation events, duration of saturation), we used high frequency water level data collected in wetland center and upland groundwater monitoring wells. In the lab, cores were re-saturated with groundwater over 15 days and after cores were fully re-saturated, core water levels were maintained for an additional 25 days. Water levels in each head tank and soil core were manually recorded on sub-daily timesteps. Rhizon soil porewater samplers were installed at 8, 20, and 40 cm below the soil surface reflecting the expected depths of the O, A, and B soil horizons across the wetland sites. Source groundwater, soil porewater, and exfiltrated surface water samples were collected daily from the soil cores and analyzed for pH, ORP, and DOM concentration (dissolved organic carbon) and DOM composition (absorbance and fluorescence metrics). Discrete measurements of CO2 and CH4 fluxes were
Time series of high-frequency sensor data measuring water temperature, dissolved oxygen, pressure, conductivity, specific conductance, total dissolved solids, chlorophyll a, phycocyanin, fluorescent dissolved organic matter, and turbidity at discrete depths in Falling Creek Reservoir, Virginia, USA in 2018-2025
We monitored water quality in Falling Creek Reservoir (Vinton, Virginia, USA; 37.30325 -79.8373) with high-frequency (10-minute) sensors in 2018-2025. All variables were measured at the deepest site of the reservoir adjacent to the dam. Falling Creek Reservoir is owned and managed by the Western Virginia Water Authority as a primary drinking water source for Roanoke, Virginia. This data product consists of one dataset compiled of depth profiles of water temperature on 1-m intervals from 0.1 to 9 m depth; dissolved oxygen at 5 m and 9 m depth; pressure at 9 m depth; and temperature, dissolved oxygen, conductivity, specific conductance, chlorophyll a, phycocyanin, total dissolved solids, fluorescent dissolved organic matter, turbidity, and pressure at ~1.6 m depth. The dataset is accompanied by a sensor maintenance log and quality assurance/quality control analysis scripts.
Time series of high-frequency sensor data measuring water temperature, dissolved oxygen, conductivity, specific conductance, total dissolved solids, chlorophyll a, phycocyanin, fluorescent dissolved organic matter, and turbidity at discrete depths, and water level in Beaverdam Reservoir, Virginia, USA in 2009-2025
We monitored water level and water quality in Beaverdam Reservoir (Vinton, Virginia, USA; 37.31288, -79.8159) with visual observations and high-frequency (10- to 15-minute resolution) sensors in 2009-2025. All variables were measured at the deepest site of the reservoir adjacent to the dam. Beaverdam Reservoir is owned and managed by the Western Virginia Water Authority as a secondary drinking water source for Roanoke, Virginia. This data package is comprised of three datasets: 1) bvre-waterlevel_2009_2025.csv, 2) bvre-sensorstring_2016_2020.csv, and 3) bvre-waterquality_2020_2025.csv. 1) bvre-waterlevel_2009_2025.csv contains water level observations of the staff gauge at a platform near the reservoir's dam by both the Western Virginia Water Authority and the Virginia Tech Reservoir Group LTREB field crew. This dataset spans 2009 to 2025, with data collection still ongoing. 2) bvre-sensorstring_2016_2020.csv consists of a water temperature profile at ~1-meter intervals from the surface of the reservoir to 10.5 m below the water, complemented by intermittent data collected by a dissolved oxygen logger deployed at 5 m or 10 m. A sonde measuring water temperature, conductivity, specific conductance, chlorophyll a, phycocyanin, total dissolved solids, dissolved oxygen, fluorescent dissolved organic matter, and turbidity was additionally deployed at ~1.5 m depth. This dataset spans 2016 to 2020, with no additional data collection beyond the last observation. The third dataset is bvre-waterquality_2020_2025.csv, with data collection still ongoing and an accompanying maintenance log. This dataset contains: a) a temperature string with 13 temperature sensors deployed ~1 m apart from the surface to 0.5 m above the sediments of the reservoir; b) two dissolved oxygen sensors, one in the middle of the string and one sensor above the sediments; and c) a pressure sensor just above the sediments. The same sonde from the first 2016-2020 dataset is also included in this 2020-2025 d
Composition and biodegradability of dissolved organic matter leached from eroding coastal soils and permafrost in seawater, from Drew Point, Alaska
Eroding permafrost coastlines export significant quantities of organic carbon (OC) to the marine environment, similar in magnitude to riverine particulate OC fluxes to the Arctic Ocean. Moreover, erosion rates are predicted to increase due to warming temperatures, declines in sea ice, and increasing waves. While erosion primarily mobilizes organic matter in the particulate form, this material can be leached to dissolved organic matter (DOM). This DOM may be incorporated by microbial communities and fuel marine food webs or decomposed to form greenhouse gases like carbon dioxide and methane. Many studies show that permafrost-derived organic matter can be rapidly decomposed in soils and freshwater, but few studies examine the fate of permafrost organic matter in seawater. To address this knowledge gap, we designed a laboratory experiment to leach coastal soils and permafrost in seawater and examine the composition and biodegradability of leached DOM. Coastal soil/sediment was cored near Drew Point, Alaska in 2019, representing three horizons found within rapidly eroding permafrost bluffs: seasonally thawed active layer soils, Holocene terrestrial soils and/or lacustrine sediments, and late-Pleistocene relict marine sediments. To measure dissolved organic carbon (DOC) leaching yields, we placed soil/sediments in Beaufort Sea seawater for 24 hours before filtering to remove particulates. To measure biodegradable dissolved organic carbon (BDOC), we conducted an aerobic incubation experiment following the methods suggested by Vonk et al. (2015). Briefly, leachates were incubated at approximately room temperature for 26 and 90 days to measure DOC loss due to remineralization and/or incorporation into microbial biomass. Additionally, we used chromophoric dissolved organic matter (CDOM) measurements and ultra-high resolution mass spectrometry (FT-ICR MS) to examine the initial leachate DOM composition. References: Vonk, J. E., Tank, S. E., Mann, P. J., Spencer, R. G. M., Tre
Molecular composition of dissolved organic matter in NTL-LTER lakes detected by Fourier-transform ion cyclotron resonance mass spectrometry
The composition of dissolved organic matter (DOM) varies widely in the environment due to distinct sources of the material and subsequent processing. DOM composition drives its reactivity in terms of many processes including photochemical reactions, microbial metabolism, and carbon cycling within water bodies. This study uses ultra-high resolution mass spectrometry via a Fourier-transform ion cyclotron resonance mass spectrometer (FT-ICR MS) to evaluate DOM composition at the molecular level to determine differences in DOM composition among the NTL-LTER lakes. Whole water samples were collected from the surface of each lake near the shore on August 18th and 19th in 2016 in. Ultraviolet-visible spectra were recorded as light absorbance can also give information about DOM composition. Additionally, concentrations of anions, cations, and pH were measured waters because these can all alter DOM reactivity in the environment. Both water chemistry and DOM composition vary widely among the lakes with the bogs displaying the most terrestrial-like signature in DOM and the oligotrophic lakes show more microbial-like or environmentally processed DOM.
Molecular composition of dissolved organic matter from Lake Mendota from June – November 2017, analyzed by Fourier-transform ion cyclotron resonance mass spectrometry
Dissolved organic matter (DOM) is a complex mixture of organic compounds found in all natural waters. Its composition affects its reactivity towards numerous processes. Its composition is a function of both its source (e.g., allochthonous or autochthonous) as well as the extent of environmental processing it has undergone (e.g., chemical or biological degradation). Fourier-transform ion cyclotron resonance mass spectrometry (FT-ICR MS) allows for the characterization of dissolved organic matter at the molecular level. The water sample was collected near the NTL-LTER research buoy on Lake Mendota. Formula assignments were made to raw mass to charge ratios detected in the mass spectrum using a custom processing script and resulting in a list of chemical formulas making up the DOM sample.
Ultraviolet-visible spectroscopy absorbances for dissolved organic matter from Lake Mendota from June – November 2017
Dissolved organic matter (DOM) is a complex mixture of organic compounds found in all natural waters. Its composition affects its reactivity towards numerous processes. Its composition is a function of both its source (e.g., allochthonous or autochthonous) as well as the extent of environmental processing it has undergone (e.g., chemical or biological degradation). Ultraviolet-visible (UV-vis) spectroscopy is an analytical technique commonly used to assess the composition of dissolved organic matter in water samples. Here, we present spectra from Lake Mendota samples collected from June - November in 2017 at the surface of Lake Mendota as well as at specific depths within the water column. All samples were collected near the NTL-LTER research buoy. Absorbance values are listed for wavelengths 200 - 800 nm for each sample.
Raw data mzXML and MATLAB code for Variation in chemical composition of dissolved organic matter during the winter to spring transition in the northern Barents Sea
<p>MATLAB code and raw data mzXML for Variation in chemical composition of dissolved organic matter during the winter to spring transition in the northern Barents Sea.</p> <p>Seawater samples were collected during three distinct periods: early winter (December 2019), late winter (March 2021), and spring (May 2021). The sampling transect extended from the northern Barents Sea into the Nansen Basin (76°N – 83°N) as part of <em>The Nansen Legacy</em> project (Research Council of Norway, RCN #276730). The molecular composition of dissolved organic matter (DOM) was analyzed using an Orbitrap mass spectrometer.</p>
Examination of protein-like fluorophores in chromophoric dissolved organic matter (CDOM) in a wetland and coastal environment for the wet and dry seasons of the years 2002 and 2003 (FCE)
Water samples are collected at the end of the dry and the wet season from all LTER sites and stored on ice until return to the lab. They are pre-filtered through pre-combusted GF/F filters and ultrafiltered and concentrated with a Pellicon 2 Mini tangential flow ultrafiltration system.Concentrated samples were then analyzed using fluorescence and SEC-HPLC. This CDOM optical study revealed the presence of two classes of compounds associated with the protein-like peak (peak T; excitation/emission (Ex/Em) maxima at around 280 nm/325 nm), which have very different chemical structures and ecological roles. In addition to proteins, we propose phenolic compounds as possible origins of peak T in coastal and wetland environments. In this study, natural water samples were obtained from subtropical rivers and estuarine environments within the Florida Coastal Everglades (FCE) ecosystem. The samples were ultra-filtered and excitation-emission fluorescence matrices (EEMs) were obtained. The EEMs showed the presence of four peaks with Ex/Em maxima at around 280 nm/325 nm (T), less than 260 nm/460 nm (A), 300 nm/412nm (M), and 350 nm/470 nm (C). To better understand the nature of peak T, the components originating this peak were separated using size exclusion chromatography (SEC) and detected by fluorescence emission at Ex/Em = 280 nm/325 nm. The elution curves revealed the presence of two elution peaks at a molecular weight of greater than 50K (void volume; T1) and around 7.6K (T2). This result suggested the need of cautious interpretation in the use of peak T as a proxy for the detection of proteinaceous materials in wetland and estuarine environments, since significant amounts of potentially interfering phenolic compounds are leached from senescent biomass in wetland and coastal ecosystems. As such EEM spectra of gallic acid an important component of hydrolysable tannins, and condensed tannins extracted from red mangroves (Rhizophora mangle) showed the presence of a peak maxima
Chemical characteristics of dissolved organic matter in an oligotrophic subtropical wetland/estuary ecosystem, Everglades National Park (FCE), South Florida from December 2001 to January 2002
The objective of this study was to investigate in detail the molecular characteristics of DOM in a sub-tropical, oligotrophic aquatic environment, namely the Florida coastal Everglades, along a freshwater wetland, mangrove fringe to estuarine transect. For this purpose, surface waters from five sites along Taylor Slough ranging from freshwater marsh to mangrove ecotone environments, as well as three sites within the Florida Bay estuary were collected for analyses. Fluorescence properties of DOM were measured for a quick assessment of DOM quality. Ultrafiltered DOM samples (UDOM; less than 0.7 um, greater than 1000 Da) were concentrated and freeze dried for the determination of bulk C composition, lignin-phenol concentration, and neutral sugar composition. These molecular characteristics were investigated by 13C-NMR spectroscopy, TMAH thermochemolysis, and hydrolysis with trifluoroacetic acid (TFA), respectively. Furthermore, UDOM samples were classified by cluster analysis based on their pyrolysis products obtained via flash pyrolysis-GC/MS.
Dissolved Organic Matter Composition in Doboy Sound and the Altamaha River near Sapelo Island, Georgia in 2012-2013
The composition of dissolved organic matter (DOM) in the Altamaha River estuary and Doboy Sound near Sapelo Island, Georgia, was investigated at the molecular level using ultrahigh-resolution mass spectrometry and stable carbon isotope analyses. DOM samples were collected in November 2012, May 2013, and September 2013 representing different hydrological regimes, including anomalously low-discharge conditions. DOM was also collected from water as it flooded and ebbed from an extensive marsh area at Sapelo Island in May 2013. The untargeted approach used allowed for identifying the DOM molecular signatures associated with different DOM sources in the estuary.
Microbially-Mediated Transformations of Estuarine Dissolved Organic Matter from Doboy Sound, Sapelo Sound and the Altamaha River near Sapelo Island, Georgia in 2012-2013
Dissolved organic matter (DOM) samples were collected from a marsh-dominated estuarine system (Altamaha River estuary, Doboy Sound and Sapelo Sound near Sapelo Island, Georgia), inoculated with native microbiological samples, and incubated in the dark for up to 70 days. Control and incubated DOM samples were then anlyzed using ultrahigh resolution mass spectrometry to investiage microbially-mediated transformations at the molecular level. Samples were collected at high tide in November 2012 and May 2013.
Seasonal Evolution of Terrigenous Dissolved Organic Matter in the South Atlantic Bight off Georgia in 2014
Six surveys of the central South Atlantic Bight (SAB) off of Georgia were conducted in 2014. The primary objective of the research cruises was to characterize estuary-shelf exchange and the dispersal of freshwater into the coastal ocean around Sapelo Island off the Georgia coast. The surveys, in April, May, July, August, September, and November, were intended to sample shelf conditions under different seasons. Most of the sampling stations were located at the mouth of the estu-aries around Sapelo Island and over the inner and mid-shelf (<60 km offshore). Eighty samples from transects extending across the shelf from the mouths of the Altamaha River and of Sapelo Sound were selected for the analyses of molecular composition using ultrahigh resolution mass spectrometry (Fourier transform ion cyclotron reso-nance mass spectrometry [FT-ICR MS]) and stable carbon iso-topic signatures (delta 13C). This data set includes spectral analysis of the DOM, including spectral slope (275-295nm wavelength), terrigenous peaks from mass spectrometry analysis, and a computed terrigenous index indicating fraction of terrigenous DOM in water samples.
Long-term trends and synchrony in dissolved organic matter characteristics in Wisconsin, USA lakes: quality, not quantity, is highly sensitive to climate
Dissolved organic matter (DOM) is a fundamental driver of many lake processes. In the past several decades, many lakes have exhibited a substantial increase in DOM quantity, measured as dissolved organic carbon (DOC) concentration. While increasing DOC is now widely recognized, fewer studies have sought to understand how characteristics of DOM (DOM quality) change over time. Quality can be measured in several ways, including the optical characteristics spectral slope (S275-295), spectral ratio (SR), absorbance at 254 nm (a254), and DOC-specific absorbance (SUVA; a254:DOC). However, long-term measurements of quality are not nearly as common as long-term measurements of DOC concentration. We used 24 years of DOC and absorbance data for seven lakes in the North Temperate Lakes Long Term Ecological Research site in northern Wisconsin, USA to examine temporal trends and synchrony in both DOC concentration and quality. We predicted lower SR and S275-295 and higher a254 and SUVA trends, consistent with increasing DOC and greater allochthony. DOC concentration exhibited both significant positive and negative trends among lakes. In contrast, DOC quality exhibited trends suggesting reduced allochthony or increased degradation, with significant long-term increases in SR in three lakes. Patterns and synchrony of DOM quality parameters suggest they are more responsive to climatic variations than DOC concentration. SUVA in particular tended to increase with greater moisture and decrease with drier conditions. These results demonstrate that DOC quantity and quality can exhibit different complex long-term trends and responses to climate components, with important implications for aquatic ecosystems.
Dissolved Organic Carbon Concentration, Dissolved Organic Matter Optical Properties, and Water Quality Indicators in the Plum Island Estuary (PIE), Massachusetts, USA (2018-2023)
This is a data set of paired in situ measurements of water quality parameters, total suspended solids concentration, and concentration and optical properties (absorption coefficient spectra and fluorescence indices) of dissolved organic matter (DOM) collected between 2018 and 2023 in the Plum Island Estuary and nearshore waters. In situ water quality measurements (salinity, temperature, optical dissolved oxygen saturation, turbidity, and dissolved organic matter fluorescence) were collected with a water quality sonde from the surface (top 1 m of water column), along with corresponding samples that were processed and analyzed in the lab for dissolved organic carbon (DOC) concentration, chromophoric DOM (CDOM), absorption coefficient spectra, DOM excitation-emission matrix (EEM) fluorescence, and total suspended sediment (TSS) concentration. The data were used in multiple studies (see manuscripts listed below) focusing on the dynamics of DOC and CDOM in the Plum Island Estuary.
Sherbo et al. 2023 Data Package. Data associated with study assessing effects of dissolved organic matter on phytoplankton productivity in boreal lakes. The majority of data was collected in 2018 at the IISD Experimental Lakes Area in Northwestern Ontario
Allochthonous dissolved organic matter (DOM) structures many physical, chemical, and biological properties of lakes, including key variables that control productivity at the base of freshwater food webs. We examined phytoplankton biomass and productivity and their drivers, across eight pristine boreal lakes with DOM ranging from 3.5 to 9.5 mg DOC L-1. Increases in DOM were associated with significant increases in epilimnetic nitrogen, phosphorus and chlorophyll a (Chl a) concentrations suggesting that nutrients associated with DOM stimulate phytoplankton biomass and productivity. Such results were misleading; there was no significant relationship between Chl a and phytoplankton biomass measured via microscopy, and results did not incorporate the effects of DOM on thermocline and euphotic depth. Chl a:biomass and Chl a: carbon ratios indicated that increases in Chl a with DOM were driven by photo-acclimation to declining light availability. Increases. Further, increases in DOM led to large declines in thermocline (~50 %) and euphotic (~75 %) depths, and depth-integrated phytoplankton biomass and primary production (~70 %).
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