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9 results for “electric double layer”
Figure 4: Nyquist diagrams ² 00 (!¿¾) = f(² 0 (!¿¾))T 166-TOWARD THE PHYSICAL BASIS OF COMPLEX SYSTEMS: DIELECTRIC ANALYSIS OF POROUS SILICON NANOCHANNELS IN THE ELECTRICAL DOUBLE LAYER LENGTH RANGE
<p>Fig.4. This behaviour denotes that the EDL is not an ideally<br> capacitor, but also is not a disipative region, depending both on the EDL<br> thickness and the frequency range of the applied ¯eld [7]. The composition<br> (by thickness) of the EDL determines essentially the dielectric response of the<br> interface system. Compared with experimental results, the dielectric pro¯le<br> of this higher length scales model, can provides a more complet description of<br> the solvent properties for a given electrode.</p>
Figure 1: EDL structure for p-Si-TOWARD THE PHYSICAL BASIS OF COMPLEX SYSTEMS: DIELECTRIC ANALYSIS OF POROUS SILICON NANOCHANNELS IN THE ELECTRICAL DOUBLE LAYER LENGTH RANGE
<p>Figure 1: EDL structure for p-Si (SCL negative charged,²F < ²FR )/aqueous<br> solvent interface. The electrostatic potential and charged atoms in solvent<br> distributions vs the distance z from the wall.</p>
Figure 3: The dependencies ² 00 (log !¿¾). The values are normalized at ² 00 max-TOWARD THE PHYSICAL BASIS OF COMPLEX SYSTEMS: DIELECTRIC ANALYSIS OF POROUS SILICON NANOCHANNELS IN THE ELECTRICAL DOUBLE LAYER LENGTH RANGE
<p>Fig.3. The conductivity relaxation occurs at<br> lowing frequencies. The form of the ²<br> 00<br> (!) = f(²<br> 0<br> (!)) diagrams changes from<br> a vertical line (a), to any deformate semicircles (b, c, d) having the angle to<br> real axe below ¼<br> 2 , Fig.4. This behaviour denotes that the EDL is not an ideally<br> capacitor, but also is not a disipative region, depending both on the EDL<br> thickness and the frequency range of the applied ¯eld [7]. The composition<br> (by thickness) of the EDL determines essentially the dielectric response of the<br> interface system. Compared with experimental results, the dielectric pro¯le<br> of this higher length scales model, can provides a more complet description of<br> the solvent properties for a given electrode.</p>
Figure 2: The dependencies ² 0 (log !¿¾). The values are normalized at ² 0 max-TOWARD THE PHYSICAL BASIS OF COMPLEX SYSTEMS: DIELECTRIC ANALYSIS OF POROUS SILICON NANOCHANNELS IN THE ELECTRICAL DOUBLE LAYER LENGTH RANGE
<p>The results of the model are shown that the frequency-dependences ²<br> 0<br> (log(!¿¾))<br> in Fig.2, ²<br> 00(log(!¿¾)) in Fig.3 and ²<br> 00<br> (²<br> 0<br> )T in Fig.4, where ²<br> 0<br> , ²<br> 00<br> are the real and<br> imaginary part, respectively, from (7), having the ¸D<br> ¸ ratio as parameter.</p>
Data and software for "Metal Pad Sensing: exploiting the electrical double layer to improve resistance-based microfluidic cell tracking, with applications to label-free mechanophenotyping"
<p>Data and software for "Metal Pad Sensing: exploiting the electrical double layer to improve resistance-based microfluidic cell tracking, with applications to label-free mechanophenotyping"</p>
Contrasting Views of the Electric Double Layer in Electrochemical CO2 Reduction: Continuum Models vs Molecular Dynamics (data for figures)
<p>This is the data used to create the figures in the article:</p> <h4>Contrasting Views of the Electric Double Layer in Electrochemical CO<sub>2</sub> Reduction: Continuum Models vs Molecular Dynamics</h4> <div>Evan Johnson and Sophia Haussener</div> <div>The Journal of Physical Chemistry C <strong>2024</strong> <em>128</em> (25), 10450-10464</div> <p>DOI: 10.1021/acs.jpcc.4c03469</p> <p>See the file "Naming conventions" for the file names and column/row meanings. </p>
Dataset for "Strain induced electrochemical behaviours of ionic liquid electrolytes in an electric double layer capacitor: Insights from molecular dynamics simulations"
<p>The datafile contains molecular dynamics simulation results for analysing the electrochemical behaviour of ionic liquid based EDLC under compression and tension.</p>
Probing the Electrical Double Layer by Operando X-ray Photoelectron Spectroscopy through a Graphene-Carbon Nanotube Composite Window
<p>Supporting information for Molecular Dynamics NAMD 2.0 simulations of BPY1,4-TFSI-Li ionic liquid mixture encased in cuboid graphene box for graphene window double layer calculations presented in submitted manuscript to Eco Mat journal.</p> <p>The files contain new developed parameters for BPY1,3-TFSI force field based on Gaussian09 DFT calculations and relevant PDB and PSF and configuration files for NAMD runs at 0, 1 and 3Volt.</p> <p>Abstract: </p> <p>The electrical double layer is known to spontaneously form at the electrode-electrolyte interface, impacting many important chemical and physical processes as well as applications including electrocatalysis, electroorganic synthesis, nanomaterial preparation, energy storage, and even emulsion stabilization. However, it has been challenging to study this fundamental phenomenon at the molecular level because the electrical double layer is deeply “buried” by the bulk electrolyte solution. Here, we report a quantitative probing of the electrical double layer of ionic liquids from the solid side of a photoelectron-transparent graphene-carbon nanotube hybrid membrane electrode using X-ray photoelectron spectroscopy. The membrane window is ultrathin (~1.5 nm), large (~1 cm<sup>2</sup>), and robust, enabling a tight seal of the electrolyte and quantitative measurement with excellent photoelectron signals. By <em>operando</em>monitoring the population changes of cations and anions in response to the applied electrical potentials, we experimentally resolve the chemical structure and dynamics of the electrical double layer, which corroborate results from molecular dynamics simulations.</p>
Supplementary Data for Manuscript "A relation of resistivity-hydraulic conductivity for fine-grained soil based on coupled electric double layer model and modified Kozeny-Carman model"
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