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7 results for “hydrazine”

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zenodo40/100

Dinitrogen Reduction and Functionalization by a Siloxide Supported Thulium-Potassium Complex for the Formation of Ammonia or Hydrazine Derivatives

<p>The dinitrogen (N2) chemistry of lanthanides remainsless developed compared to the d-block metals and lanthanide-promoted N2 functionalization chemistry in well-defined lanthanidecomplexes remains elusive. Here we report the synthesis andcharacterization (SQUID, EPR, DFT, X-Ray) of the siloxidesupported heterobimetallic (Tm/K) complexes[{KTm(OSi(OtBu)3)3}2(&mu;-&eta;2:&eta;2-N2)] (1) and [K3{Tm(OSi(OtBu)3)3}2(&mu;-&eta;2:&eta;2-N2)] (2). Complex 2 provides a rare example of a metalcomplex of the triply reduced N23- radical. The structure of 2 differsfrom the few previously reported N23- complexes as it presents twoTm and three K cations binding the N23- radical, facilitating N2functionalization. Notably, the K3Tm2-bound N23- moiety reacts withexcess H+ to form NH4Cl in 18% yield, and with MeOTf at roomtemperature to yield the dimethyl hydrazido complex[K2{Tm(OSi(OtBu)3)3}2(&mu;-(CH3)NN(CH3))] (3). Protonolysis of 3yields MeHN-NMeH&middot;2HCl in 18 % yield.</p>

opencc-by-4.0Oct 2024View details →
zenodo28/100

Figure 3 from: Demchenko SА, Fedchenkova YА, Yeromina HО, Herashenko IV, Berdnyk OH, Demchenko AM (2021) The synthesis of N-(4-aryl-thiazol-2-yl)-N1-(4,5,6,7-tetrahydro-3H-azepin-2-yl)-hydrazine hydrobromides and the cardioprotective activity of (41-methoxyphenyl-thiazol-2-yl) derivative. Pharmacia 68(1): 141-146. https://doi.org/10.3897/pharmacia.68.e58788

Figure 3 Smooth muscle preparations miographic study methodic scheme, where: 1 peristaltic pump 2 thermostat 3 amplifier 4 Capacitive tensometric sensor 5 work chamber (heated wtih thermostat) 6 analog-to-digital converter 7 personal computer.

opencc-by-4.0Jan 2021View details →
zenodo28/100

Figure 1 from: Demchenko SА, Fedchenkova YА, Yeromina HО, Herashenko IV, Berdnyk OH, Demchenko AM (2021) The synthesis of N-(4-aryl-thiazol-2-yl)-N1-(4,5,6,7-tetrahydro-3H-azepin-2-yl)-hydrazine hydrobromides and the cardioprotective activity of (41-methoxyphenyl-thiazol-2-yl) derivative. Pharmacia 68(1): 141-146. https://doi.org/10.3897/pharmacia.68.e58788

Figure 1 Structural formulas for active components of Levocarnitin (а), Mildronate (b) and N-[4-(41-methoxyphenyl)-thiazol-2-yl]-N1-(4,5,6,7-tetrahydro-3H-azepin-2-yl)-hydrazine hydrobromide (5 b)

opencc-by-4.0Jan 2021View details →
zenodo28/100

Scheme 1 from: Demchenko SА, Fedchenkova YА, Yeromina HО, Herashenko IV, Berdnyk OH, Demchenko AM (2021) The synthesis of N-(4-aryl-thiazol-2-yl)-N1-(4,5,6,7-tetrahydro-3H-azepin-2-yl)-hydrazine hydrobromides and the cardioprotective activity of (41-methoxyphenyl-thiazol-2-yl) derivative. Pharmacia 68(1): 141-146. https://doi.org/10.3897/pharmacia.68.e58788

Scheme 1 Synthesis of N-(4-aryl-thiazol-2-yl)-N1-(4,5,6,7-tetrahydro-3Н-azepin-2-yl)-hydrazine hydrobromides (5 a–d). Where: 1, 3, 5: a) R=R1=H b) R=OCH3, R1=H; c) R=Cl, R1=H; d) RR1=-OCH2CH2O-.

opencc-by-4.0Jan 2021View details →
zenodo24/100

Figure 2 from: Demchenko SА, Fedchenkova YА, Yeromina HО, Herashenko IV, Berdnyk OH, Demchenko AM (2021) The synthesis of N-(4-aryl-thiazol-2-yl)-N1-(4,5,6,7-tetrahydro-3H-azepin-2-yl)-hydrazine hydrobromides and the cardioprotective activity of (41-methoxyphenyl-thiazol-2-yl) derivative. Pharmacia 68(1): 141-146. https://doi.org/10.3897/pharmacia.68.e58788

Figure 2 Mildronate (meldonium).

opencc-by-4.0Jan 2021View details →
geo20/100

Effect of hydrazine on gene expression of FE1 cells

GEO Series GSE215974. Mus musculus. 32 samples. Type: Expression profiling by high throughput sequencing.

openGEO-OpenOct 2022View details →
geo16/100

Research on the mode of action of a novel 2-cyclopropyl-4-aminopyrimidine hydrazine compound (4k) for control of cyanobacteria

GEO Series GSE194275. Synechocystis sp. PCC 6803. 9 samples. Type: Expression profiling by high throughput sequencing.

openGEO-OpenMay 2022View details →

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