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2 results for “mercury cycle”

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zenodo36/100

Mercury abundance and isotopic composition in granitic rocks: Implications for Hg cycling in the upper continental crust

<p>Mercury (Hg) is a highly volatile metal exhibiting both isotope mass-dependent (MDF, defined as &delta;<sup>202</sup>Hg) and mass-independent (MIF, expressed as &Delta;<sup>199</sup>Hg) fractionation. Assessing the Hg isotopic composition of the upper continental crust is crucial for the use of this new geochemical tool for petrogenetic tracing, particularly for understanding crust-mantle interaction. Here, we report Hg isotopic compositions of granitic rocks with distinct source affinity (I-, A-, and S-type) and of metasedimentary enclaves from the South China Craton. The results of more than 100 rock samples show large &delta;<sup>202</sup>Hg variations of -2.03 to 0.47 &permil; and relatively small &Delta;<sup>199</sup>Hg variations of -0.16 to 0.09 &permil;. The S-type granites studied here exhibit higher &delta;<sup>202</sup>Hg values (-0.58 to 0.00 &permil;; n=57) than their sedimentary protoliths (metasedimentary enclaves; -2.03 to -0.91 &permil;; n=7), suggesting significant Hg-MDF during magmatic processes. The &Delta;<sup>199</sup>Hg values of S-type granites (-0.08 to 0.09 &permil;) are indistinguishable from their sedimentary protoliths (-0.16 to 0.02 &permil;), suggestive of the absence of Hg-MIF during crustal anatexis and subsequent magmatic differentiation. The I- and A-type granites studied have smaller &Delta;<sup>199</sup>Hg variations of -0.11 to 0.04 &permil; (n=28) and -0.07 to 0.04 &permil; (n=15), respectively, but are within the range of the S-type granites. The compositional range of all granite variants may be explained by the variable intensity of large-scale MASH (melting-assimilation-storage-homogenization) processes. Our new data combined with previously published data of igneous, sedimentary and metamorphic rocks allow us to estimate that the upper continental crust (UCC) has a Hg abundance of 13.5 ppb and a weighted average &delta;<sup>202</sup>Hg of -1.15 &plusmn; 1.01 &permil; (2SD), which are higher than the corresponding value of the primitive mantle, indicating the enrichment of Hg and &delta;<sup>202</sup>Hg in the UCC. However, the weighted average &Delta;<sup>199</sup>Hg value of the UCC (0.03 &plusmn; 0.15 &permil;; 2SD) is undistinguished from the primitive mantle, suggesting no obvious Hg-MIF during the formation and differentiation of the continental crust.</p>

opencc-by-4.0Sep 2023View details →
zenodo28/100

Dataset of paper "Environmental life cycle assessment of UV-C LEDs vs. mercury lamps and oxidant selection for diclofenac degradation"

<p>Dataset of paper "Environmental life cycle assessment of UV-C LEDs vs. mercury lamps and oxidant selection for diclofenac degradation":</p> <ul> <li><span><span>Absolute impact across all categories of the Environmental Footprint (EF) for each treatment and scenario&nbsp;</span></span></li> <li><span><span>Relative impacts as percentages&nbsp;</span></span></li> </ul>

opencc-by-4.0Jun 2024View details →

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