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9 results for “oxygen electrode”

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zenodo52/100

Dataset for "Methodology of Evaluating the Activation Energy of Oxygen Reduction Reaction on Pt-based Electrodes"

<p>High temperature proton-exchange membrane fuel cell (HT-PEMFC) technology is widely studied alternative to current energy conversion technologies based on fossil fuels. Compared to solid oxide fuel cells (SOFCs), HT-PEMFCs allow more flexibility and demand less operation control due to their lower temperature. On the other hand, HT-PEMFCs show an advantage over low-temperature PEMFCs in terms of less demand on the purity of the H2 used, the possibility to recover the generated heat, lower water management requirements, and easy heat management. One of the critical limitations of HT-PEMFC operation is a slow kinetics of the cathodic reduction of O2 (ORR) due to presence of H3PO4 which ensures proton conductivity in the system. Electrochemical dynamic methods such as cyclic voltammetry or linear sweep voltammetry (LSV) can be used to determine the kinetic parameters of ORR. These measurements can provide information on the Tafel slope and exchange current density (jex) of the ORR. However, performing these measurements under conditions relevant for HT-PEMFC operation is challenging due to presence highly concentrated H3PO4 and elevated temperature. First, determination of the kinetic parameters requires correct assessment of equilibrium potential of ORR (EORR). The value of the EORR is generally influenced by the activity (fugacity) of the reactants and products and the temperature, a discussion of the appropriate standard states of the components is also necessary. Second, the relationship between the jex and the reaction rate constant (k&deg;), necessary for calculation of activation energy ( ), must be known. It includes consideration of the likely reaction mechanism. In this paper, the methodology for appropriate determination of &nbsp;was developed and used for estimation of &nbsp;of ORR from LSV curves measured on commercially available Pt/C catalyst under HT-PEMFC relevant conditions. In particular, the measurements were carried out using a rotating glassy carbon rod disk electrode (RRE) in purified 98 wt.% H3PO4 (as electrolyte) at temperatures of 120, 140, 160, 180 &deg;C. Though the treatment was developed in context of ORR and HT-PEMFC, the approach is generally applicable to any electrochemical reaction.</p>

opencc-by-4.0Aug 2024View details →
zenodo52/100

Dataset of "Structural Development on Ru and RuO2 Electrodes during Oxygen Evolution – an operando soft X-ray Absorption Spectroscopy Approach"

<p>Time resolved in-situ X-ray absorption spectroscopy (XAS) in soft X-ray region was used to characterize polarized interphase on Ru and Ru oxide based electrodes under oxygen evolution reaction (OER) conditions. XAS spectra were used to align the type and population of oxygen-containing species formed at electrodes at anodic potentials with local electronic structure of the OER catalyst. The operando soft XAS data do not identify a single rate limiting process at potentials negative to 1.4 V vs Ag/AgCl. Individual intermediates of the oxygen evolution process coexist at the surface at potentials preceding the actual OER onset. The OER is accompanied with redistribution of the electron density resulting for a start of the catalytic cycle reflecting increased population of oxygen vacancies at the surface. The observed spectral behavior indicates a confinement of the OER to the coordination unsaturated sites (cus) at the surface.&nbsp;</p>

opencc-by-4.0Jun 2024View details →
zenodo52/100

Dataset of "Nickel-cobalt spinel-based oxygen evolution electrode for zinc-air flow battery"

<p>Following dataset provides all measured data that were collected on nickel (Ni) based electrodes for the oxygen evolution reaction. The electrodes were following: nickel (Ni) pristine mesh (PM), catalysed mesh (CM), nickel pristine foam (PF), catalysed foam (CF). Catalyst was NiCo2O4. Firstly, the catalysed electrodes were prepared and characterized by SEM, EDS and XRD. The electrodes were characterized in three different arrangements: in electrolysis non-flow arrangement, in a flow electrolysis cell and in ZAFB according to the manuscript.</p>

opencc-by-4.0Oct 2024View details →
zenodo44/100

NewSOC, supplementary information to WT2.5.4 "Cells with honeycomb structured oxygen electrodes": electrochemical and post-mortem data sets.

<p>These are data set, related to participation of the IEN in project NewSOC. It includes results of the SEM-EDS analysis of the cells with hexagonal current collecting net and electrochemical performance data, both EIS and C-V characteristics. Results are grouped in zip archives, named according to cell design, &ldquo;infill-net&rdquo;.</p> <p>Compositions:</p> <p>LNF &ndash; LaNi<sub>0.6</sub>Fe<sub>0.4</sub>O<sub>3</sub> (net)</p> <p>LSC &ndash; La<sub>0.6</sub>Sr<sub>0.4</sub>CoO<sub>3-</sub><sub>d</sub> (infill)</p> <p>LSF &ndash; La<sub>0.5</sub>Sr<sub>0.5</sub>FeO<sub>3-</sub><sub>d</sub> (infill)</p> <p>LSCCF &ndash; La<sub>0.6</sub>Sr<sub>0.4</sub>Co<sub>0.15</sub>Cu<sub>0.05</sub>Fe<sub>0.8</sub>O<sub>3-</sub><sub>d </sub>(net)</p> <p>PCM &ndash; Pr<sub>0.5</sub>Ca<sub>0.5</sub>MnO<sub>3 </sub>(net)</p> <p>BSCFM &ndash; Ba<sub>0.5</sub>Sr<sub>0.5</sub>Co<sub>0.725</sub>Fe<sub>0.2</sub>Mo<sub>0.075</sub>O<sub>3-</sub><sub>d</sub> (infill)</p> <p>&nbsp;</p> <p><strong>Data presentation. </strong></p> <p><em>C-V characteristics:</em></p> <p>This is text files, generated by Zahner galvanostat, with self-decriptional titles.</p> <p>&ldquo;05iv_650c_100h2+100h2o_500air.txt&rdquo; &ndash; &nbsp;measurement at 650&deg;C, 100 mL/min H<sub>2</sub> and 100 mL/min H<sub>2</sub>O on fuel side, 500 mL/min of air on air side.</p> <p><em>EIS data:</em></p> <p>EIS results were extracted from proprietary binary files, generated by Zahner galvanostat, and raw data is generally meaningless except the owners of such hardware. So, extracted EIS can be found in Excel files, used in analysis, in sheet &ldquo;Experimental&rdquo;. Other sheets in xlsx include some metadata (&ldquo;info&rdquo;), results of the equivalent circuit fit (&ldquo;fit&rdquo;) and some plots. Fit results might not be relevant. &nbsp;</p> <p><em>SEM</em></p> <p>Post-mortem results presented as SEM images (tif or jpg files) and pdf files with results of the EDS analysis.</p> <p><strong>LSC-LNF </strong></p> <p><em>(air flow 1 L/min, current density 0.25 A/cm<sup>2</sup>)</em></p> <p>test_1_07: &nbsp;</p> <p>03_eis20200917142808.xlsx &ndash; EIS, SOFC, 700&deg;C, Flows L/min: F:0.2 H<sub>2</sub>;</p> <p>05_eis20200917123105.xlsx &ndash; EIS, SOFC, 700&deg;C, flows L/min: F:0.1 H<sub>2</sub>+ 0.1 H<sub>2</sub>O;</p> <p>08_eis20200917123857.xlsx &ndash; EIS, SOFC, 700&deg;C, flows L/min: F:0.1 H<sub>2</sub>+ 0.1 H<sub>2</sub>O;</p> <p>10_eis20200917131537.xlsx &ndash; EIS, SOEC, 700&deg;C, flows L/min: F:0.1 H<sub>2</sub>+ 0.1 H<sub>2</sub>O;</p> <p>test_1_08:</p> <p>03_eis20200917125707.xlsx &ndash; EIS, SOFC, 700&deg;C, Flows L/min: F:0.2 H<sub>2</sub>;</p> <p>09_eis20200917130019.xlsx &ndash; EIS, SOEC, 700&deg;C, flows L/min: F:0.09 H<sub>2</sub>+ 0.21 H<sub>2</sub>O;</p> <p>10_eis20200917130600.xlsx &ndash; EIS, SOFC, 700&deg;C, flows L/min: F:0.06 H<sub>2</sub>+ 0.14 H<sub>2</sub>O;</p> <p>12_eis20200917130737.xlsx &ndash; EIS, SOEC, 700&deg;C, flows L/min: F:0.12 H<sub>2</sub>+ 0.28 H<sub>2</sub>O;</p> <p>test_3_14:</p> <p>01_eis20210517102042.xlsx&ndash; EIS, SOFC, 700&deg;C, Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2</sub>; 05_eis20210517102625.xlsx&ndash; EIS, SOFC, 700&deg;C, flows L/min: F:0.1 H<sub>2</sub>+ 0.1 H<sub>2</sub>O;</p> <p>07_eis20210517102305.xlsx&ndash; EIS, SOEC, 700&deg;C, flows L/min: F:0.06 H<sub>2</sub>+ 0.14 H<sub>2</sub>O;</p> <p>SEM</p> <p><em>(post-mortem after test_1_07)</em></p> <p>ogniwo_310_2020&nbsp; ****.jpg - surface</p> <p>&nbsp;</p> <p><strong>BSCMF-PCM</strong></p> <p><em>(SOFC, air flow 0.5 L/min)</em></p> <p>test_2_14</p> <p>01eis_700c_cc4a_100h2+100n2_500air_eqc20220110112836.xlsx &ndash;700&deg;C, 0.25 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2</sub></p> <p>02eis_700c_cc4a_100h2+100h2o_500ai_eqc20220110112724.xlsx &ndash;700&deg;C, 0.25 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>04eis_650c_cc3a_100h2+100h2o_500ai_eqc20220110112503.xlsx&ndash;650&deg;C, 0.1875 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>06eis_650c_cc3a_100h2+100n2_500air_eqc20220110112332.xlsx &ndash;650&deg;C, 0.1875 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2</sub>;</p> <p>07eis_625c_cc3a_100h2+100n2_500air_eqc20220110112214.xlsx &ndash;625&deg;C, 0.125 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2</sub>;</p> <p>08eis_625c_cc3a_100h2+100h2o_500ai_eqc20220110111834.xlsx&ndash;625&deg;C, 0.125 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>test_1_67</p> <p>01_eqc20220831134628.xlsx&ndash;700&deg;C, 0.125 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2</sub></p> <p>02_eqc20220831134724.xlsx - 700&deg;C, 0.25 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>04_eqc20220831135442.xlsx&ndash;650&deg;C, 0.0625 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2</sub>;</p> <p>06_eqc20220831135622.xlsx - 650&deg;C, 0.0625 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>08_eqc20220831135801.xlsx - 625&deg;C, 0.0625 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>09_eqc20220831135933.xlsx &ndash;650&deg;C, 0.0625 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2</sub>;</p> <p>SEM</p> <p><em>(post-mortem of the test_2_14)</em></p> <p>493-2021-1.pdf, 493-2021-1i.pdf, 493-2021-2.pdf, 493-2021-2-2.pdf, 493-2021-2-3.pdf &ndash;cross-sections with EDS</p> <p>493_2021_*_**.tif&nbsp; - cross-sections</p> <p>&nbsp;</p> <p><strong>BSCMF-LSCCF</strong></p> <p><em>(SOFC, air flow 0.5 L/min)</em></p> <p>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; test_2_08</p> <p>01_eis20211104144342.xlsx - 700&deg;C, 0.25 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2 </sub></p> <p>03eis_700c__eis20211108102241.xlsx - 700&deg;C, 0.25 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>04eis_700c__eis20211108102401.xlsx - 700&deg;C, 0.25 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>08eis__eis20211110094642.xlsx - 650&deg;C, 0.1875&nbsp; A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2 </sub></p> <p>10eis__eis20211110094945.xlsx - 650&deg;C, 0.1875 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>11eis__eis20211110101358.xlsx - 625&deg;C, 0.125 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>13eis__eis20211110100837.xlsx- 625&deg;C, 0.125 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2</sub>;</p> <p>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; test_2_26</p> <p>04_eqc20220817114103.xlsx - 700&deg;C, 0.25 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>06_eqc20220817121529.xlsx - 700&deg;C, 0.25 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2 </sub></p> <p>07_eqc20220802084119.xlsx - 650&deg;C, 0.1875&nbsp; A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1</p> <p>08_eqc20220802084616.xlsx - 650&deg;C, 0.1875 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>10_eqc20220802150705.xlsx - 625&deg;C, 0.125 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2</sub>;</p> <p>11_eqc20220802150108.xlsx - 625&deg;C, 0.125 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>SEM</p> <p><em>(post-mortem of the test_2_26)</em></p> <p>661_BSCMF_LSCCF_p.pdf &nbsp;&ndash; cross-section with EDS</p> <p>661_BSCMF_LSCCF_PM.pdf - surface with EDS</p> <p>661_BSCMF_LSCCF_p_01.tif, 661_BSCMF_LSCCF_p_02.tif, 661_BSCMF_LSCCF_p_03.tif, 661_BSCMF_LSCCF_p_04.tif&nbsp; -&nbsp; cross-section, infill zone</p> <p>661_BSCMF_LSCCF_p_05.tif, 661_BSCMF_LSCCF_p_06.tif - cross-section, net zone zone</p> <p>661_BSCMF_LSCCF_PM_**.tif&nbsp; - surface</p> <p>&nbsp;</p> <p><strong>LSF-LSCCF</strong></p> <p><em>(SOFC, air flow 0.5 L/min)</em></p> <p>test_1_65</p> <p>01_eqc20220816105347.xlsx - 700&deg;C, 0. 1875 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2</sub>;</p> <p>02_eqc20220816105941.xlsx - 700&deg;C, 0. 1875 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>04_eqc20220816112311.xlsx - 650&deg;C, 0. 125 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>06_eqc20220816111640.xlsx - 650&deg;C, 0.125 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2</sub>;</p> <p>07_eqc20220816142436.xlsx- 625&deg;C, 0.0625 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2</sub>;</p> <p>08_eqc20220816142842.xlsx-625&deg;C, 0.625 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>SEM</p> <p><em>(post-mortem) </em></p> <p>663_LSF_LSCCF_p.pdf &ndash; cross-section with EDS</p> <p>663_LSF_LSCCF_PM.pdf - surface with EDS</p> <p>663_LSF_LSCCF_P_GR_**.tif &ndash; cross-section of the cell</p> <p>663_LSF_LSCCF_P_LSCCF_**.tif &ndash; surface of the LSCCF grid</p> <p>663_LSF_LSCCF_PM_**.tif - surface of the LSF infill</p> <p>&nbsp;</p> <p>&nbsp;</p> <p><strong>LSF-PCM</strong></p> <p><em>(SOFC, air flow 0.5 L/min)</em></p> <p>tests_1_66</p> <p>01_eqc20220831133210.xlsx - 700&deg;C, 0. 125 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2</sub></p> <p>02_eqc20220831133409.xlsx - 700&deg;C, 0. 125 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2</sub></p> <p>03_eqc20220831133928.xlsx - 700&deg;C, 0. 125 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>05_eqc20220831134048.xlsx - 650&deg;C, 0.0625&nbsp; A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2</sub>;</p> <p>06_eqc20220831134142.xlsx - 650&deg;C, 0.0625 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>08_eqc20220831134237.xlsx - 625&deg;C, 0.0625 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 H<sub>2</sub>O;</p> <p>10_eqc20220831134412.xlsx - 625&deg;C, 0.0625 A/cm<sup>2</sup> Flows L/min: F:0.1 H<sub>2</sub>+0.1 N<sub>2</sub>;</p> <p>SEM</p> <p><em>(post-mortem)</em></p> <p>658_LSF_PCM_p.pdf &ndash; cross-section with EDS</p> <p>658_LSF_PCM_PM.pdf - surface with EDS</p> <p>658_LSF_PCM_P_LSF_**.tif&nbsp; &ndash; cross-section, infill zone</p> <p>658_LSF_PCM_P_pcm_**.tif - cross-section, net zone</p> <p>658_LSF_PCM_PM_**.tif - surface</p> <p><strong>description.pdf </strong>-&nbsp;pdf version of this information.</p>

opencc-by-4.0Jun 2023View details →
zenodo28/100

Characterization, modelling, and optimization of high-performance nano-columnar micro–Solid Oxide Cell oxygen electrodes

<p>Dataset containing all the data used in the article entitled &quot;Characterization, modelling, and optimization of high-performance nano-columnar micro&ndash;Solid Oxide Cell oxygen electrodes&quot;.</p>

opencc-by-4.0Sep 2023View details →
geo24/100

Transcriptomic analyses of Lysinibacillus varians GY32 respiring with electrode or oxygen [RNA-seq G]

GEO Series GSE165754. Lysinibacillus varians. 6 samples. Type: Expression profiling by high throughput sequencing.

openGEO-OpenJan 2021View details →
geo24/100

Transcriptomic analyses of Lysinibacillus varians GY32 respiring with electrode or oxygen

GEO Series GSE165755. Lysinibacillus varians. 12 samples. Type: Expression profiling by high throughput sequencing.

openGEO-OpenJan 2021View details →
geo24/100

Transcriptomic analyses of Lysinibacillus varians GY32 respiring with electrode or oxygen [RNA-seq K]

GEO Series GSE165753. Lysinibacillus varians. 6 samples. Type: Expression profiling by high throughput sequencing.

openGEO-OpenJan 2021View details →
geo12/100

S. oneidensis MR-1 with electrode, Fe(III)citrate and oxygen as electron acceptor

GEO Series GSE20379. Shewanella oneidensis MR-1. 9 samples. Type: Expression profiling by array.

openGEO-OpenFeb 2011View details →

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International Brain Laboratory public data

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