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559 results for “RH”
Kinetics assessment of the homogeneously catalyzed hydroformylation of ethylene on a Rh-catalyst
<p>Supplementary Information. Section S1, description of dependence of rate and equilibrium coefficients on selected standard state, reaction entropies of reaction steps at different standard states, and derivation of rate equations; Section S2, experimental conditions of data sets selected for model regression and model validation; Section S3, calculation of enthalpies and entropies of solvation explained in more detail and obtained values; and Section S4, calculation of entropies of coordination explained in detail and resulting values</p>
High-resolution T2M and RH simulated using WRF-ARW over Cyprus for 2015
<p>Meteorological data generated over Cyprus for the year 2015 using the open-source, community-based, state-of-the-art Weather Research and Forecasting (WRF-ARW) Model. The model was configured according to the operational numerical weather forecasts of the Cyprus Department of Meteorology (DoM). The meteorological fields, generated with a nested configuration setup, are at an ultra-fine spatiotemporal resolution (<em>i.e.,</em> 2 km horizontal grid spacing and 1-hour temporal frequency).</p>
APEX beta NW site: hourly soil temperature, soil moisture, air temperature and RH, photosynthetically active radiation (PAR), and rain.
This dataset contains hourly averages of air temperature and RH, soil temperature and moisture, PAR, and rain. This basic environmental data supports the other research that is going on at this site.
APEX gamma black spruce site: hourly soil temperature, soil moisture, air temperature and RH and photosynthetically active radiation (PAR).
This dataset contains hourly averages of air temperature and RH, soil temperature and moisture, and PAR. This basic environmental data supports the other research that is going on at this site.
Composition and electrical resistance results of a Ir-Pd-Pt-Rh-Ru composition spread thin film materials library
<p>The dataset contains the results of electrical resistance measurement and composition analysis of a thin film composition spread materials library. </p> <p>342 measurement areas were evaluated for chemical composition using energy dispersive X-ray spectroscopy and electrical resistance using a 4-point probe.</p> <p>CSV columns:</p> <p>x: x-coordinate of materials library in µm</p> <p>y: y-coordinate of materials library in µm</p> <p>Ir: relative chemical composition in at.%</p> <p>Pd: relative chemical composition in at.%</p> <p>Pt: relative chemical composition in at.%</p> <p>Rh: relative chemical composition in at.%</p> <p>Ru: relative chemical composition in at.%</p> <p>Resistance: electrical resistance in Ohm</p> <p> </p> <p>This dataset is supplementary information for an associated publication. A link to the publication will be provided after publishing.</p>
Fig 2 in Soluble total antigen derived from Toxoplasma gondii RH strain prevents apoptosis, but induces anti-apoptosis in human monocyte cell line
Fig 2. This schematic overview suggests signaling pathways of apoptosis. Apoptosis is induced through either the extrinsic pathway or intrinsic pathway. Toxoplasma gondii can prevent cell apoptosis via inhibition of cytochrome c release from the mitochondria into the cytosol, inhibition of cas-3, -6, -7, and -9 via blocking the mitochondrial pathway, and blocking cas-8 by external pathways. The parasite may also suppress pro-apoptotic protein (Bax) and induce anti-apoptotic Bcl-2 proteins and is able to activate transcription factors STAT6 and STAT3-miR-17-92-Bim pathway to inhibit apoptosis. Some proteins of T. gondii such as ROP18 plays a role in Fas/ CD95-mediated apoptosis to inhibit this process. Similarly ROP16 phosphorylates STAT3 and STAT6 to inhibit cell death. Original (S. Nemati).
Fig 1 in Soluble total antigen derived from Toxoplasma gondii RH strain prevents apoptosis, but induces anti-apoptosis in human monocyte cell line
Fig 1. The comparison of the expression levels of Bcl-2 (A), Mcl-1 (B), Cas-7 (C), Cas-3 (D), and Bax (E) in THP-1 cell line regarding different concentrations of the soluble total antigen of Toxoplasma gondii (Nicolle et Manceaux, 1908) STAg. NS: not significant; * P value <0.05; ** P value <0.01; *** P value <0.001.
The promotional role of Mn in CO2 hydrogenation over Rh-based catalysts from a surface organometallic chemistry approach
<p>Rh-based catalysts modified by transition metals have been intensively studied for CO2 hydrogenation due<br> to their high activity. However, understanding the role of promoters at the molecular level remains<br> challenging due to the ill-defined structure of heterogeneous catalysts. Here, we constructed welldefined RhMn@SiO2 and Rh@SiO2 model catalysts via surface organometallic chemistry combined with thermolytic molecular precursor (SOMC/TMP) approach to rationalize the promotional effect of Mn in CO2 hydrogenation. We show that the addition of Mn shifts the products from almost pure CH4 to a mixture of methane and oxygenates (CO, CH3OH, and CH3CH2OH) upon going from Rh@SiO2 to RhMn@SiO2. In situ X-ray absorption spectroscopy (XAS) confirms that the MnII is atomically dispersed in the vicinity of metallic Rh nanoparticles and enables to induce the oxidation of Rh to form the Mn–O–Rh interface under reaction conditions. The formed interface is proposed to be key to maintaining Rh+ sites, which is related to suppressing the methanation reaction and stabilizing the formate species as evidenced by in situ DRIFTS to promote the formation of CO and alcohols<br> </p>
AMIP and AMIP-P4K simulation dataset with Park-RH and Gauss-PDF cloud scheme
<p>This dataset includes AMIP and AMIP-P4K simulations using Park-RH and Gauss-PDF cloud schemes, respectively. </p> <p>Park-RH cloud scheme is the default cloud macrophysical scheme in NCAR CAM5. </p> <p>Gauss-PDF cloud scheme is a statistical cloud scheme, developed by Qin et al. (2018). </p> <p>All simulations are AMIP-type simulations from 1979 to 1988. The monthly output is archived here. </p> <p>Details of the model setup and the difference of two cloud schemes could be found in its related submitted manuscript. </p>
h-BN in the making: The surface chemistry of borazine on Rh(111)
<p>Herein, we present the raw data and the evaluated files (including a corresponding data assignment) affiliated with the research article "h-BN in the making: The surface chemistry of borazine on Rh(111)", accepted for publication in The Journal of Chemical Physics.</p>
DFT Calculated xyz Files in Support of "Bidentate Rh(I)-Phosphine Complexes for the C-H Activation of Alkanes: Computational Modelling and Mechanistic Insight"
<p>Theoretically calculated xyz files for propane, carbon monoxide, butyraldehyde and multiple Rh-phosphine complexes as well as transition states relevant for the C-H activation and subsequent carbonylation of alkanes.</p> <p>All quantum chemical simulations were performed using the Gaussian 16 software package. Closed-shell equilibrium structures, i.e., minima and transition states (TSs) as well as electronic properties of educts, intermediates, and products involved in the C-H activation of propane (methyl group activation) and subsequent steps mediated by the Rh complexes were obtained at the DFT level of theory. The range-separated B97XD functional was employed. The def2-SVP basis set and the respective effective core potential (ECP) were utilized for all atoms. TSs were fully optimized at the same level of theory using the rational function optimization (RFO) approach as well as nudged elastic band (NEB) method as implemented in the pysisyphus<sup> </sup>software suite. Subsequently, a vibrational analysis was carried out for each stationary point to verify that a minimum or first-order saddle point was obtained on the 3<em>N</em>-6-dimensional potential energy (hyper)surface (PES).</p>
Bromine Adsorption and Thermal Stability on Rh(111): A Combined XPS, LEED and DFT Study [doi: 10.1002/cphc.202300510]
<p>Primary data, meta data, and corresponding lists of figures & tables are included. [doi: 10.1002/cphc.202300510]</p>
Drift of Pt-Rh thermocouples in emf and in temperature terms at 1324 °C
<p>Dataset containing drift of selected Pt-Rh thermocouples which are part of a multi-wire thermocouple. Drift is in emf terms and in temperature terms. Drift was measured by exposing the thermocouples to a temperature of approximately 1324 °C, with periodic in-situ calibration using a Co-C 'fixed-point' point cell (melting point 1324.29 °C).</p>
Pt‑40%Rh Versus Pt‑6%Rh Thermocouples: An emf‑Temperature Reference Function for the Temperature Range 0 °C to 1769 °C
<p>Data for the associated paper, DOI https://doi.org/10.1007/s10765-021-02895-w</p> <p>The paper describes the metrological characterization of the highly stable Pt40%Rh/Pt-6%Rh thermocouples to determine their reference function in the temperature range between 0 °C and 1769 °C. The preparation of the Pt-40%Rh/Pt-6%Rh thermocouples is described, as well as the measurement procedures and the measurement results of comparison and fxed point measurements for the determination of the reference function with low uncertainties.</p>
Datset and scripts for "Systematic occurrence cycle of typical RH-profiles during the MJO: evidence for ubiquitous pre-moistening"
<p>This repository contains data and scripts for the GRL paper:</p> <p><strong>Systematic occurrence cycle of typical RH-profiles during the MJO: evidence for ubiquitous pre-moistening</strong></p> <p>by Carsten Abraham, Colin Goldblatt, and Adrian Matthews.</p> <p>The <strong>data </strong>directory holds postprocessed data for the plots.</p> <p>The <strong>scripts</strong> directory holds the scripts to produce plots in the paper. </p> <p>The clustering and information about the raw data can be retrieved from </p> <p>https://journals.ametsoc.org/view/journals/atsc/79/9/JAS-D-21-0270.1.xml</p> <p>and</p> <p>https://journals.ametsoc.org/view/journals/atsc/aop/JAS-D-22-0119.1/JAS-D-22-0119.1.xml</p>
A computational insight on the aromatic amino acids conjugation with [Cp*Rh(H2O)3]2+ by using the MTD/FMO3 approach.
<p>The zip file contains the 3D coordinates of the optimized structures, obtained by sampling each 1 ps of the EC1, EC2 and EC3 trajectories (MTD and MD calculations) and used as input geometries for FMO3 calculations.</p>
Efficacy of High-dose Intravenous Immunoglobulin Therapy for Hyperbilirubinemia Due Rh Hemolytic Disease
ClinicalTrials.gov study NCT00288600. IPD Sharing: Not stated. Countries: 1. Publications: 1.
A validated physical model of the thermoelectric drift of Pt-Rh thermocouples above 1200 °C
<p>Data associated with a validated physical model of the thermoelectric drift of Pt-Rh thermocouples above 1200 °C (Metrologia 57 (2020) 025009) https://doi.org/10.1088/1681-7575/ab71b3</p>
Heptamethyl Indenyl (Ind*) Enables Diastereoselective Benzamidation of Cyclopropenes via Rh(III)-Catalyzed C-H Activation
<p>Supporting Information: DFT optimised structures as described in the title paper</p>
Figure 4: The Pacer RH domain basic triad controls subcellular localization [FINAL]
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